[Cu(imidazole)(N-naphthylidene-glycine(2-))] | 850310-15-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [Cu(imidazole)(N-naphthylidene-glycine(2-))]
• CAS: 850310-15-5
• 化学式: C₁₆H₁₃CuN₃O₃
• 分子量: 358.844
• InChiKey: XHSMFASAFKPZJA-MOEKMLTRSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  咪唑 、 copper(II) choride dihydrate 、 聚甘氨酸 、 2-羟基-1-萘甲醛 以 乙醇 、 水 为溶剂， 以74%的产率得到[Cu(imidazole)(N-naphthylidene-glycine(2-))]
  参考文献：
  名称：

  Synthesis, Characterization, and Electrochemical Adsorption Study on Mercury Electrode of New Ternary Cu(II) Complexes ofN‐Naphthylideneamino Acids with Imidazoles

  摘要：

  A new series of Cu(II) complexes of naphthylideneamino acid Schiff bases (H(2)naph:aa) as a primary ligand and imidazole or 2-methylimidazole (B) as a secondary ligand has been synthesized and characterized. The analytical data and physical characterization have proved that the complexes are four coordinate with the general formula [Cu(II)(naph:aa)B]. The structure of the complexes is suggested to be square-planar. The adsorption of the formed complexes on a hanging mercury drop electrode (HMDE) was performed in 0.1 mol dm(-3) KCl solution utilizing cyclic voltammetric and chronocoulometric techniques. The results indicate that an adsorption of copper(II) adducts occurs on the mercury electrode and the amount adsorbed expressed as excess surface coverage, F, was determined. The values of F calculated chronocoulometrically are almost the same as those calculated by cyclic voltammetry.

  DOI：

  10.1081/sim-200030135