2-(3-(2,5-di(4-hydroxymethylphenyl)-4-(4-(diphenylamino)styryl)styryl)-5,5-dimethylcyclohex-2-enylidene)malononitrile | 1346452-64-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2-(3-(2,5-di(4-hydroxymethylphenyl)-4-(4-(diphenylamino)styryl)styryl)-5,5-dimethylcyclohex-2-enylidene)malononitrile
• CAS: 1346452-64-9
• 化学式: C₅₃H₄₅N₃O₂
• 分子量: 755.959
• InChiKey: YXKGZHSMISRNOL-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  1,3,3-trimethyl-5-dicyanovinyl-1-cyclohexene 、 2,5-di(4-hydroxymethylphenyl)-4-(4-(diphenylamino)styryl)benzaldehyde 在 哌啶 作用下， 以 四氢呋喃 为溶剂， 反应 6.0h， 以79%的产率得到2-(3-(2,5-di(4-hydroxymethylphenyl)-4-(4-(diphenylamino)styryl)styryl)-5,5-dimethylcyclohex-2-enylidene)malononitrile
  参考文献：
  名称：

  The preparation of two-dimensional spindle-type chromophores for second-order nonlinear optical materials

  摘要：

  A series of two-dimensional spindle-type chromophores has been synthesized. The detailed synthetic procedure was reported. The factors that influence the nonlinear optical properties such as the donors and acceptor character have been investigated. The chemical structures of the target products have been confirmed by IR, UV-Vis and NMR spectroscopy, elemental and thermal analysis. The spindle-type chromophores have been used to prepare host-guest doped films which exhibited very good thermal and temporal stability. The nonlinear electro-optical coefficients of the host-guest doped films were measured by the Teng-Man technique and gave values in the range from 21 to 29 pm/V. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2011.08.021