lead(II) N-methyldiethanolaminate | 880645-65-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: lead(II) N-methyldiethanolaminate
• CAS: 880645-65-8
• 化学式: C₅H₁₁NO₂*Pb
• 分子量: 324.348
• InChiKey: IXBBRNGPWFERSO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -2.74
• 重原子数：
  9.0
• 可旋转键数：
  4.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  49.36
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为产物：
  描述：

  N-甲基二乙醇胺 、 lead(II) oxide 以 甲苯 为溶剂， 以96%的产率得到lead(II) N-methyldiethanolaminate
  参考文献：
  名称：

  Cost efficient preparation of lead aminoalkoxides directly from lead(II) oxide

  摘要：

  The preparation of lead(II) aminoalkoxides has been demonstrated from the direct reaction of aminoalcohols with lead(II) oxide. The denticity of the aminoalcohols determined the facility of the reactions, the rate increasing with the number of hydroxyls. Thus, [Pb(dmae)(2)], 1, [Pb(mdea)](infinity), 2, and [Pb(teaH)](2), 3 (dmaeH = dimethylaminoethanol, mdeaH(2) = N-methyldiethanolamine, and teaH(3) = triethanolamine) have been prepared in high yields and characterized by H-1 and C-13 NMR. The X-ray crystal structure analyses of 2 and 3 are described. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2005.09.021