| 183659-38-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• CAS: 183659-38-3
• 化学式: C₄₈H₃₂Cu₂N₄O₄*H₂O
• 分子量: 873.914
• InChiKey: MEOKACQUYOXPOD-RMHZUEAHSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-[[5-[(2-Hydroxyphenyl)methylideneamino]naphthalen-1-yl]iminomethyl]phenol 、 copper diacetate 以 四氢呋喃 、 甲醇 、 乙醇 为溶剂， 以78%的产率得到
  参考文献：
  名称：

  Synthesis and Characterisation of Binuclear Cu(II), Ni(II) and Co(II) Chelates with Tetradentate Schiff Base Ligands Derived from 1,5-Diaminonaphthalene

  摘要：

  A new series of copper(II), nickel(II) and cobalt(II) chelates containing the binucleating tetradentate Schiff base ligands N,N'-bis(salicylidene)-1,5-diaminonaphthalene (H(2)L), N,N'-bis(3-methoxysalicylidene)-1,5-diaminonaphthalene (H(2)L') and N,N'-bis(4-hydroxysalicylidene)-1,5-diaminonaphthalene (H(2)L '') have been synthesized. These compounds have been characterized by elemental analyses, conductivity measurements, magnetic susceptibility, thermoanalyses (TG-DTA), infrared and electronic spectral data. The results suggest that the Schiff bases function as tetradentate ligands coordinating through the ONNO donor system and indicate a binuclear structure for the Cu(II) complexes with pseudo-tetrahedral geometry and binuclear structures for the Co(II) and Ni(II) complexes with pseudo-octahedral geometry. All complexes are non-electrolytes.

  DOI：

  10.1080/00945719608005148