(PPh3)(1,10-phenanthroline)Cu(NC(S)SN2) | 94365-53-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: (PPh3)(1,10-phenanthroline)Cu(NC(S)SN2)
• 英文别名: Cu(I)(4-thia-1,2,3-triazole-5-thione)(PPh3)(1,10-phenanthroline) complex；copper(1+);1,10-phenanthroline;1-thia-2,3-diaza-4-azanidacyclopent-2-ene-5-thione;triphenylphosphane
• CAS: 94365-53-4
• 化学式: C₃₁H₂₃CuN₅PS₂
• 分子量: 624.209
• InChiKey: MAVYMYSVHTUBPE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (PPh3)(1,10-phenanthroline)Cu(NC(S)SN2) 生成 三苯基瞵硫
  参考文献：
  名称：

  LA, MONICA, G.;ARDIZZOIA, G.;CENINI, S.;PORTA, F., J. ORGANOMET. CHEM., 1984, 273, N 2, 263-273

  摘要：

  DOI：
• 作为产物：
  描述：

  二硫化碳 、 (PPh3)(1,10-phenanthroline)CuN3 在 三苯基膦 作用下， 以 苯 为溶剂， 生成 (PPh3)(1,10-phenanthroline)Cu(NC(S)SN2)
  参考文献：
  名称：

  The chemical behaviour of the azido group bonded to copper(I): Synthesis and reactivity of thiothiatriazolato and alkynyl complexes

  摘要：

  DOI：

  10.1016/0022-328x(84)80531-8

文献信息

• Copper(I) and silver(I) azide complexes containing N-donor ligands
  作者：C. Pettinari

  DOI：10.1016/s0277-5387(01)00895-6

  日期：2001.9

  From the interaction of imidazole-type ligand L (L = imidazole (im), 1-methylimidazole (1-meim), 2-methylimidazole (2-meim), 4-methylimidazole (4-meim), benzimidazole (bzim), 1-benzylimidazole (bnim)) with [Cu(N-3)(PPh3)(2)](2) the new mononuclear [Cu(N-3)(PPh3)(2)(L)] and dinuclear [Cu-2(N-3)(2)(PPh3)(3)(L)] species have been obtained. Chelating bidentate ligands (L-2 = 2.2-bipyridyl (bipy), 1,10-phenanthroline (phen) or 2,9-dimethyl-1,10-phenanthroline (cupr)) react with [M(N-3)(PPh3)(2)](2) (M = Cu or Ag) yielding [M(N-3)(PPh3)(L-2)]. The S-donors 1-methyl-2-imidazol-2(3H)-thione (Hmimt), 2-benzothiazolethiol (Hbtt) and 2-pyridinethiol (Hpyt) react with [Cu(N-3)(PPh3)(2)](2) in ethanol undergoing deprotonation and yielding [Cu(mimt)(Ph3P)](n), [Cu(btt)](n) and [Cu(pyt)](n), respectively. On the contrary, Hmimt and imidazoline-2(1,3H)thione (Himt) react in diethyl ether with [Cu(N-3)(PPh3)(2)](2) yielding [Cu(N-3)(Hmimt)(3)] and [Cu(N-3)(PPh3)(Himt)], respectively. P(o-tolyl)(3) is able to displace the less basic phosphine PPh3 from [Cu(N-3)(PPh3)(cupr)] yielding the complex [Cu(N-3)P(o-tolyl)(3)}(cupr)]. 1,3-Bis(diphenylphosphino)propane (dppp) reacts with [Cu(N-3)(PPh3)(cupr)] yielding the complex [Cu-2(N-3)(2)(dppp)(3)]. [Cu(N-3)(PPh3)(2)(im)] and [Cu(N-3)(PPh3)(phen)] react with CS2 in benzene, in presence of excess of PPh3 forming [Cu(SCN)(PPh3)(2)] and [Cu(tz)(PPh3)(phen)] (Htz = 4-thia-1,2,3-triazole-5-thione), respectively. [Ag(N-3)(PPh3)(cupr)] reacts slowly with excess of CS2 in diethyl ether giving [Ag(tz)(cupr)], whereas the same reaction in benzene in excess of PPh3 yields immediately [Ag(SCN)(PPh3)(2)]. From the reaction of [Ag(N-3)(PPh3)(cupr)] with cyCN the complex [Ag(N-3)(cyCN)(PPh3)(cupr)] formed. All derivatives were characterized by IR and far-IR data, conductivity, H-1 NMR and in some cases also with P-31H-1} NMR and molecular weight measurements. (C) 2001 Elsevier Science Ltd. All rights reserved.