4-[(4-氨基-2-甲基环己基)甲基]-3-甲基环己烷-1-胺 | 13190-57-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 4-[(4-氨基-2-甲基环己基)甲基]-3-甲基环己烷-1-胺
• 英文名称: 3,3'-dimethyl-4,4'-methanediyl-bis-cyclohexylamine
• 英文别名: Bis-(4-amino-2-methyl-cyclohexyl)-methan；3,3'-Dimethyl-4,4'-methandiyl-bis-cyclohexylamin；Bis(p-amino-2-methyl--cyclohexyl)methane；4-[(4-amino-2-methylcyclohexyl)methyl]-3-methylcyclohexan-1-amine
• CAS: 13190-57-3
• 化学式: C₁₅H₃₀N₂
• 分子量: 238.417
• InChiKey: NTGJOYPFNABNES-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  聚合甲醛 、 4-[(4-氨基-2-甲基环己基)甲基]-3-甲基环己烷-1-胺 在 甲醇 、 水 、 镍 作用下， 100.0 ℃ 、5.88 MPa 条件下， 生成 bis-(4-dimethylamino-2-methyl-cyclohexyl)-methane
  参考文献：
  名称：

  DE838892

  摘要：

  公开号：
• 作为产物：
  描述：

  4-(4-氨基-2-甲基苄基)-3-甲基苯胺 在 氨 、 uranium(VI) trioxide 、 thorium dioxide 、 镍 、 zinc(II) oxide 作用下， 200.0~220.0 ℃ 、49.03 MPa 条件下， 生成 4-[(4-氨基-2-甲基环己基)甲基]-3-甲基环己烷-1-胺
  参考文献：
  名称：

  DE875653

  摘要：

  公开号：

文献信息

• Compound having silsesquioxane skeleton and its polymer
  申请人：Inagaki Jyun-ichi

  公开号：US20050009982A1

  公开（公告）日：2005-01-13

  The present invention relates to a compound represented by Formula (1) and a polymer obtained using the compound: wherein R 1 is phenyl which may have substituents, Q 1 is hydrogen, halogen, alkyl having 1 to 10 carbon atoms, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexenyl or phenyl in which optional hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms, and Q 2 is a group represented by Formula (2) wherein the code < represents a bonding point with silicon, l, m, n and p are independently 0, 1, 2 or 3, A 1 to A 4 are independently a single bond, 1,4-cyclohexylene, 1,4-cyclohexenylene, a condensed ring group having 6 to 10 carbon atoms which is a divalent group, or 1,4-phenylene, Z 0 to Z 3 are independently a single bond, —CH═CR—, —C≡C—, —COO—, —OCO—, or alkylene having 1 to 20 carbon atoms, and Z 4 is a single bond, —CH═CH—, —C≡C—, —COO—, —OCO—, or alkylene having 1 to 20 carbon atoms. And Y 1 in Formula (1) is the group defined in Claim 1.

  本发明涉及一种由式（1）表示的化合物和使用该化合物获得的聚合物：其中R1是苯基，可能具有取代基；Q1是氢、卤素、具有1至10个碳原子的烷基、环丙基、环丁基、环戊基、环己基、环己烯基或苯基，其中可选的氢原子可被卤素或具有1至5个碳原子的烷基取代；Q2是由式（2）表示的基团，其中代码<表示与硅的连接点，l、m、n和p独立地为0、1、2或3，A1至A4独立地为单键、1,4-环己亚基、1,4-环己烯亚基、具有6至10个碳原子的缩合环基团，为二价基团，或1,4-苯亚基，Z0至Z3独立地为单键、—CH═CR—、—C≡C—、—COO—、—OCO—或具有1至20个碳原子的烷基，Z4为单键、—CH═CH—、—C≡C—、—COO—、—OCO—或具有1至20个碳原子的烷基。式（1）中的Y1是权利要求1中定义的基团。
• Verification of translation
  申请人：Inagaki Jyun-ichi

  公开号：US20070190344A1

  公开（公告）日：2007-08-16

  A compound represented by Formula (1) and a polymer obtained using the compound: wherein R 1 is phenyl which may have substituents, Q 1 is hydrogen, halogen, alkyl having 1 to 10 carbon atoms, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexenyl or phenyl in which optional hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms, Q 2 is a group represented by Formula (2): wherein the code < represents a bonding point with silicon, l, m, n and p are independently 0, 1, 2 or 3, and A 1 to A 4 , Z 0 to Z 4 and Y 1 are defined in the specification.

  公式（1）所表示的化合物和使用该化合物制得的聚合物：其中R1是苯基，可以有取代基；Q1是氢、卤素、具有1至10个碳原子的烷基、环丙基、环丁基、环戊基、环己烯基或苯基，其中可选氢原子可以被卤素或具有1至5个碳原子的烷基所取代；Q2是由公式（2）表示的基团：其中代码<表示与硅的连接点，l、m、n和p独立地为0、1、2或3，A1至A4、Z0至Z4和Y1在规范中有定义。
• COMPOUND HAVING SILSESQUIOXANE SKELETON AND ITS POLYMER
  申请人：INAGAKI Jyun-ichi

  公开号：US20120178894A1

  公开（公告）日：2012-07-12

  The present invention relates to a compound represented by Formula (1) and a polymer obtained using the compound: wherein R 1 is phenyl which may have substituents, Q 1 is hydrogen, halogen, alkyl having 1 to 10 carbon atoms, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cyclohexenyl or phenyl in which optional hydrogen may be replaced by halogen or alkyl having 1 to 5 carbon atoms, <—Z 0 A 1 -Z 1  l A 2 -Z 2  m A 3 -Z 3  n A 4  p -Z 4 —  (2) and Q 2 is a group represented by Formula (2): wherein the code < represents a bonding point with silicon, l, m, n and p are independently 0, 1, 2 or 3, A 1 to A 4 are independently a single bond, 1,4-cyclohexylene, 1,4-cyclohexenylene, a condensed ring group having 6 to 10 carbon atoms which is a divalent group, or 1,4-phenylene, Z 0 to Z 3 are independently a single bond, CH═CH—, —C≡C—, —COO—, —OCO—, or alkylene having 1 to 20 carbon atoms, and Z 4 is a single bond, —CH═CH—, —C≡C—, —COO—, —OCO—, or alkylene having 1 to 20 carbon atoms. And Y 1 in Formula (1) is the group defined in claim 1.

  本发明涉及一种由公式（1）表示的化合物以及使用该化合物获得的聚合物：其中R1是苯基，可以具有取代基，Q1是氢、卤素、1至10个碳原子的烷基、环丙基、环丁基、环戊基、环己烯基或苯基，其中可选的氢原子可以被卤素或1至5个碳原子的烷基所取代，<—Z0A1-Z1lA2-Z2mA3-Z3nA4p-Z4—（2）和Q2是由公式（2）表示的基团：其中代码<表示与硅的连接点，l、m、n和p独立地为0、1、2或3，A1至A4独立地为单键、1,4-环己基、1,4-环己烯基、具有6至10个碳原子的紧凑环基团，或1,4-苯基，Z0至Z3独立地为单键、CH═CH—、—C≡C—、—COO—、—OCO—或具有1至20个碳原子的烷基，Z4为单键、—CH═CH—、—C≡C—、—COO—、—OCO—或具有1至20个碳原子的烷基。公式（1）中的Y1是权利要求1中定义的基团。
• SELF&minus;REACTIVE&sol;CURABLE WATER&minus;BASED SOLID ADHESIVE AND METHOD OF BONDING WITH THE SELF&minus;REACTIVE&sol;CURABLE WATER&minus;BASED SOLID ADHESIVE
  申请人：KONISHI CO., LTD.

  公开号：EP1431366A1

  公开（公告）日：2004-06-23

  Self-curable water-based solid adhesives ofthisinvention include the following components (A), (B), (C), and (D): (A) an anionic-group-containing polymer terminally having an alkoxysilyl group, the polymer being a reaction product of a compound (A1) containing no anionic group and having plural isocyanate-reactive groups, a compound (A2) having an anionic group and plural isocyanate-reactive groups, a polyisocyanate compound (A3), and an alkoxysilane compound (A4) containing an isocyanate-reactive group; (B) a basic compound; (C) water; and (D) a gelling agent. The self-curable water-based solid adhesives of the present invention can be applied with good workability, have good fitting after attachment, have good adhesion to plastics, metals and glass and exhibit excellent heat resistance and water resistance after curing. They are highly safe to humans and the environment. They also have excellent shape retention and slidability and can be easily applied. In addition, they can bond adherends by contact bonding despite that they are water-based solid adhesives. Accordingly, the self-curable water-based solid adhesives of this invention are very useful as stick adhesives.

  本发明的自固化水基固体粘合剂包括以下成分 (A)、(B)、(C) 和 (D)： (A) 末端具有烷氧基硅烷基团的含阴离子基团聚合物，该聚合物是不含阴离子基团且具有多个异氰酸酯反应基团的化合物 (A1)、具有阴离子基团和多个异氰酸酯反应基团的化合物 (A2)、多异氰酸酯化合物 (A3) 和含有异氰酸酯反应基团的烷氧基硅烷化合物 (A4) 的反应产物； (B) 碱性化合物 (C) 水；以及 (D) 胶凝剂。 本发明的自固化水基固体粘合剂在使用时具有良好的可操作性，粘合后具有良好的贴合性，与塑料、金属和玻璃具有良好的粘合性，固化后具有优异的耐热性和耐水性。它们对人体和环境高度安全。它们还具有出色的形状保持性和滑动性，并且易于涂抹。此外，尽管它们是水基固体粘合剂，但可以通过接触粘合的方式粘合被粘物。因此，本发明的自固化水基固体粘合剂作为粘性粘合剂非常有用。
• AQUEOUS SILYLATED URETHANE COMPOSITION, AQUEOUS ADHESIVES FOR WRAPPING, AND AQUEOUS CONTACT ADHESIVES
  申请人：KONISHI CO., LTD.

  公开号：EP1607423A1

  公开（公告）日：2005-12-21

  A water-based silylated urethane composition is used as a water-based adhesive that has high safety, develops satisfactory tackiness in a short time and has excellent initial bond strength. The water-based silylated urethane composition contains following Components (A), (B) and (C): (A) a urethane prepolymer containing an anionic group and a tertiary amino group and having a terminal alkoxysilyl group, the urethane prepolymer (A) being a reaction product of an anionic-group-free polyol compound (A1), an anionic-group-containing polyol compound (A2), a compound (A3) containing a tertiary amino group and an isocyanate-reactive group, a polyisocyanate compound (A4), an alkoxysilane compound (A5) containing an isocyanate-reactive group, and an amine-based chain extender (A6); (B) a basic compound; and (C) water

  一种水基硅烷化聚氨酯组合物可用作水基粘合剂，它具有很高的安全性，能在短时间内产生令人满意的粘性，并具有出色的初始粘合强度。水基硅烷化聚氨酯组合物包含以下成分（A）、（B）和（C）： (A) 含有阴离子基团和叔氨基且具有末端烷氧基硅烷基团的聚氨酯预聚物，聚氨酯预聚物 (A) 是不含阴离子基团的多元醇化合物 (A1)、含阴离子基团的多元醇化合物 (A2) 的反应产物、一种含有叔氨基和异氰酸酯反应基团的化合物 (A3)、一种多异氰酸酯化合物 (A4)、一种含有异氰酸酯反应基团的烷氧基硅烷化合物 (A5) 和一种胺基扩链剂 (A6)； (B) 碱性化合物；以及 (C) 水