(E)-4-[2-(3,4,5-tripropoxyphenyl)ethenyl]benzaldehyde | 253598-60-6

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: (E)-4-[2-(3,4,5-tripropoxyphenyl)ethenyl]benzaldehyde
• 英文别名: (E)-4-(3,4,5-tripropoxystyryl)benzaldehyde；4-[(E)-2-(3,4,5-tripropoxyphenyl)vinyl]benzaldehyde；4-[(E)-2-(3,4,5-tripropoxyphenyl)ethenyl]benzaldehyde
• CAS: 253598-60-6
• 化学式: C₂₄H₃₀O₄
• 分子量: 382.5
• InChiKey: JROPBYZVTDISBN-FMIVXFBMSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  28
• 可旋转键数：
  12
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,3,5-tris(diethoxyphosphorylmethyl)benzene 、 (E)-4-[2-(3,4,5-tripropoxyphenyl)ethenyl]benzaldehyde 在 potassium tert-butylate 作用下， 以 四氢呋喃 为溶剂， 以88%的产率得到(E,E,E,E,E,E)-1,3,5-tris{2-{4-[2-(3,4,5-tripropoxyphenyl)ethenyl]phenyl}ethenyl}benzene
  参考文献：
  名称：

  Dendrimers consisting of stilbene or distyrylbenzene building blocks synthesis and stability

  摘要：

  On the basis of Wittig-Homer reactions and protection group techniques compound 7 for the core and the components 9a-c and 11a-c for the dendrons were prepared and linked in the final step. The convergent synthesis yielded constitutionally and configurationally pure dendrimers (2a-c, 2a'-c') which consist of distyrylbenzene units. Their thermo-oxidative stability in the presence of air was studied by chemiluminescence and compared to the dendrimers 1 consisting of stilbene units, (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(99)00823-6
• 作为产物：
  描述：

  对苯二甲醛缩二乙醛 、 diethyl 3,4,5-tripropoxybenzylphosphonate 在 potassium tert-butylate 、 盐酸 作用下， 以 四氢呋喃 为溶剂， 以66%的产率得到(E)-4-[2-(3,4,5-tripropoxyphenyl)ethenyl]benzaldehyde
  参考文献：
  名称：

  Dendrimers consisting of stilbene or distyrylbenzene building blocks synthesis and stability

  摘要：

  On the basis of Wittig-Homer reactions and protection group techniques compound 7 for the core and the components 9a-c and 11a-c for the dendrons were prepared and linked in the final step. The convergent synthesis yielded constitutionally and configurationally pure dendrimers (2a-c, 2a'-c') which consist of distyrylbenzene units. Their thermo-oxidative stability in the presence of air was studied by chemiluminescence and compared to the dendrimers 1 consisting of stilbene units, (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(99)00823-6

文献信息

• Poly(propylene imine) dendrimers functionalized with stilbene or 1,4-distyrylbenzene chromophores
  作者：Andrea Schulz、Herbert Meier

  DOI：10.1016/j.tet.2007.08.064

  日期：2007.11

  Two generations of dendritic nanoparticles were prepared, which contain (E)-stilbene or (E, E)-1,4-distyrylbenzene chromophores in the 4 or 8 terminal positions of the propylene imine dendrons. The compounds show a highly efficient photoreactivity. On prolonged irradiation all stilbenoid chromophores were destroyed by oligomerization (crosslinking) and the typical absorption and fluorescence of the chromophores disappeared completely. (C) 2007 Elsevier Ltd. All rights reserved.
• Dendrimers consisting of stilbene or distyrylbenzene building blocks synthesis and stability
  作者：Matthias Lehmann、Bernhard Schartel、Manfred Hennecke、Herbert Meier

  DOI：10.1016/s0040-4020(99)00823-6

  日期：1999.11

  On the basis of Wittig-Homer reactions and protection group techniques compound 7 for the core and the components 9a-c and 11a-c for the dendrons were prepared and linked in the final step. The convergent synthesis yielded constitutionally and configurationally pure dendrimers (2a-c, 2a'-c') which consist of distyrylbenzene units. Their thermo-oxidative stability in the presence of air was studied by chemiluminescence and compared to the dendrimers 1 consisting of stilbene units, (C) 1999 Elsevier Science Ltd. All rights reserved.

表征谱图