(1R,4R,6R,7R,10S,13S)-4-Chloromethyl-13-hydroxy-10,13-dimethyl-3,5-dioxa-tricyclo[5.3.3.0^1,6]tridecan-9-one | 104597-40-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环己烷
• 英文名称: (1R,4R,6R,7R,10S,13S)-4-Chloromethyl-13-hydroxy-10,13-dimethyl-3,5-dioxa-tricyclo[5.3.3.0^1,6]tridecan-9-one
• CAS: 104597-40-2
• 化学式: C₁₄H₂₁ClO₄
• 分子量: 288.771
• InChiKey: QLIXOTTVUBXMFN-JOJVEKOVSA-N

反应信息

• 作为产物：
  描述：

  (2aR,2a1R,4S,4aS,6R,7S,9aR,10R)-3,3-dichloro-2a1,7-dimethylhexahydro-1H-2,11-dioxa-6,9a,4-(epiethane[1,1,2]triyl)cycloocta[cd]pentalene-2a,4a,7(2a1H,5H)-triol 在 sodium hydroxide 作用下， 以 甲醇 为溶剂， 反应 4.0h， 生成 、 (1R,4R,6R,7R,10S,13S)-4-Chloromethyl-13-hydroxy-10,13-dimethyl-3,5-dioxa-tricyclo[5.3.3.0^1,6]tridecan-9-one 、 (1R,4S,6R,7R,10S,13S)-4-Chloromethyl-13-hydroxy-10,13-dimethyl-3,5-dioxa-tricyclo[5.3.3.0^1,6]tridecan-9-one
  参考文献：
  名称：

  Hypochlorite-promoted transformations of trichothecenes. 2. Fragmentation-rearrangement of the primary product from verrucarol

  摘要：

  DOI：

  10.1021/jo00374a037