| 202465-42-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• CAS: 202465-42-7
• 化学式: C₁₀H₁₁O₂*C₃₀H₃₃GeO₆
• 分子量: 725.375
• InChiKey: WDHCFLURXBOWNQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-羟基-5-异丙基-2,4,6-环庚三烯-1-酮 、 甲氧基锗 以 neat (no solvent) 为溶剂， 以55%的产率得到
  参考文献：
  名称：

  Structure of (tropolonato)₄M-Type Compounds (M = Si, Ge, Sn)

  摘要：

  T4M (M = Si, Ge, Sn; T = tropolonato)-type compounds were synthesized by reactions of tropolone with tetramethoxysilane, tetramethoxygermane, and tetrachlorostannane, respectively. X-ray and NMR analyses have shown that, both in the solid state and in solution, T4Si exists as an ion pair of a hexacoordinate silicocation (T3Si+) with an associated tropolone anion (T-), while T4Sn has an octacoordinate structure. The geometry around the tin atom is best described as a bicapped trigonal prism distorted toward a dodecahedron, in which the eight oxygen atoms of four tropolonato ligands are coordinated to a tin atom with an average Sn-O bond distance-of 2.168 Angstrom. Features of NMR and UV-vis spectra of T4Ge are similar to those of T4Si, indicating ion pairing between T3Ge+ and T- in solution; the black color of the solid of T4Ge is suggestive of the ion pairing in the solid-state as well, whereas single crystals suitable for X-ray analysis have not been obtained.

  DOI：

  10.1021/om970937h