4-[3-(4-氧代戊烷-2-亚基氨基)丙基亚胺]戊烷-2-酮 | 6310-78-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 4-[3-(4-氧代戊烷-2-亚基氨基)丙基亚胺]戊烷-2-酮
• 英文名称: N,N'-bis(1-methyl-3-oxobutylidene)-1,3-propanediamine
• 英文别名: N,N'-1,3-propylene bis(2,4-pentanedioneimine)；1,3-Bis-<2-acetyl-1-methyl-vinylamino>-propan；Bis-acetylaceton-trimethylendiimin；4-[3-(4-Oxopentan-2-ylideneamino)propylimino]pentan-2-one
• CAS: 6310-78-7
• 化学式: C₁₃H₂₂N₂O₂
• 分子量: 238.33
• InChiKey: JZRFURRRYACETB-UHFFFAOYSA-N

物化性质

• 熔点：
  51 °C
• 沸点：
  357.9±37.0 °C(Predicted)
• 密度：
  0.98±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0
• 重原子数：
  17
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  58.9
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 海关编码：
  2922399090

反应信息

• 作为反应物：
  描述：

  nickel(II) nitrate hexahydrate 、 4-[3-(4-氧代戊烷-2-亚基氨基)丙基亚胺]戊烷-2-酮 以 甲醇 、 水 为溶剂， 生成 [Ni(bis(acetylacetonato)propylene-1,3-diimine)]
  参考文献：
  名称：

  Binary Roles of Schiff Bases as Capping Agent and Precursor for Synthesis of Metallic Nickel Ultrafine Nanoparticles

  摘要：

  This study focused on the synthesis and characterization of nickel nanoparticles by simple precipitation method. The various Schiff bases such as ethylenediamine (acacen), 1,3-propylenediamine (acacpn), and butane-1,4-diamine (acacbn) acetyl acetonate were prepared and were used for preparing of nickel-Schiff base complexes and then, these complexes as precursor were reduced in the presence of KBH4, for the first time. In addition, the anti-aggregation effect of prepared Schiff bases was compared with common surfactants and results demonstrated that the huge ligands can be considered as novel surfactants. The obtained nickel nanoparticles were characterized by XRD, TEM, HRTEM, FT-IR, SEM, and EDS.

  DOI：

  10.1080/15533174.2013.862824
• 作为产物：
  描述：

  1,3-丙二胺 、 乙酰丙酮 以 xylene 为溶剂， 生成 4-[3-(4-氧代戊烷-2-亚基氨基)丙基亚胺]戊烷-2-酮
  参考文献：
  名称：

  1,2-和1,3-二羰基化合物与1,3-二胺的反应：一些新的1,4-二氮杂dia

  摘要：

  乙二醛亚硫酸氢钠加成化合物与2,4-二氨基戊烷二盐酸盐反应生成5,7-二甲基六氢-1,4-二氮杂-2--2-酮，但乙二醛一水合物在碱性条件下与1,3-二氨基丙烷和2,4-二氨基戊烷反应产生更复杂物质的条件。环己烷-1,2-二酮与1,3-二氨基丙烷缩合形成2,3,4,6,7,8-六氢-1 H -1,5-苯并二氮杂,,但二亚胺由两个二羰基化合物分子形成1，3-二氨基丙烷与苯甲酰，樟脑醌和靛红的反应产生了二胺之一。复杂的产品是从邻醌和二氨基丙烷获得的。1,3-二酮和1,3-二胺反应生​​成由两个酮分子和一个胺分子形成的开链化合物。2,3-二氢-1 H-1，4-二氮杂apparent显然是由丙二醛和乙二胺形成的，但是1，2-二氨基环己烷与丙二醛反应生成1，2-双（2-甲酰基乙烯基氨基）环己烷。

  DOI：

  10.1039/j39690002044

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: U: SVol.E2, 1.7.5, page 60 - 104
  作者：

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ni: MVol.C2, 7.11, page 719 - 724
  作者：

  DOI：——

  日期：——
• Sharma, R. K.; Singh, R. V.; Tandon, J. P., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1980, vol. 19, # 4, p. 378 - 379
  作者：Sharma, R. K.、Singh, R. V.、Tandon, J. P.

  DOI：——

  日期：——
• Mital, S. P.; Singh, R. V.; Tandon, J. P., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1980, vol. 10, p. 327 - 348
  作者：Mital, S. P.、Singh, R. V.、Tandon, J. P.

  DOI：——

  日期：——
• Copper(II) complexes with Schiff bases: Structures and thermal behavior
  作者：S. I. Dorovskikh、N. V. Kuratieva、S. V. Tkachev、S. V. Trubin、P. A. Stabnikov、N. B. Morozova

  DOI：10.1134/s0022476614060092

  日期：2014.11

  Ligands with Schiff bases are obtained in the condensation of propylenediamine (pda) or 2,2-dimethylpropylenediamine (dmpda) with acetylacetone (Hacac) in the 1:2 molar ratio. The ligands are characterized by the elemental analysis methods, T (melt) = 90-92 A degrees C for pda(Hacac)(2) (pda(acac)(2) is N,N'-propylene-bis(acetylacetoniminato) (2-)), T (melt) = 84-86 A degrees C for dmpda(Hacac)(2) (dmpda(acac)(2) is N,N'-2,2-dimethylpropylene-bis(acetylacetoniminato) (2-)). The tautomerism of the ligands is established by the single crystal X-ray diffraction (XRD) analysis, IR spectroscopy, and H-1, C-13 NMR spectrometry. The synthesized complexes [Cu(pda(acac)(2))] (1), T (melt) = 121-122 A degrees C and [Cu(dmpda(acac)(2))] (2), T (melt) = 156-158 A degrees C are studied by the XRD method. In both complexes, copper atoms have a planar square geometry, and the chelate bond lengths and angles are: Cu-O a parts per thousand Cu-N 1.903(2)-1.942(3) , a O-Cu-N = 94.44(12)-94.99(12)A degrees for 1 and Cu-O a parts per thousand Cu-N 1.909(1)-1.943(2) , a O-Cu-N = 94.63(6)A degrees for 2. By the thermogravimetric method it is found that both complexes can be passed practically quantitatively into the gas phase.