3',3':N,N-bi-<3-amino-2,2'-bi-1,4-naphthoquinolyl> | 138552-10-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: 3',3':N,N-bi-<3-amino-2,2'-bi-1,4-naphthoquinolyl>
• CAS: 138552-10-0
• 化学式: C₄₀H₁₈N₂O₈
• 分子量: 654.592
• InChiKey: JTXXZXDHTGWHOK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.89
• 重原子数：
  50.0
• 可旋转键数：
  0.0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  168.14
• 氢给体数：
  2.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  3',3':N,N-bi-<3-amino-2,2'-bi-1,4-naphthoquinolyl> 反应 0.5h， 以0.05 g的产率得到6,7-Dihydro-6,7-diaza-pentaphene-5,8,13,14-tetraone
  参考文献：
  名称：

  Photolysis of 3,3′-diamino-2,2′-bi-1,4-naphthoquinonyl

  摘要：

  Pyrex filtered sunlight irradiation of an acetic anhydride of 3,3'-diamino-2,2'-bi-1,4-napthoquinonyl unexpectedly led to the formation of 3',3':N,N-bi[3-amino-2,2'-bi-1,4-napthoquinonyl] which contains only two secondary amino groups. The structure of the photoproduct was elucidated from a FAB mass spectrometric as well as H-1 and C-13 n.m.r. study.

  DOI：

  10.1016/s0040-4020(01)96178-2
• 作为产物：
  描述：

  3,3'-diamino-2,2'-bi-1,4-naphthoquinonyl 以 乙酸酐 为溶剂， 反应 120.0h， 以0.38 g的产率得到3',3':N,N-bi-<3-amino-2,2'-bi-1,4-naphthoquinolyl>
  参考文献：
  名称：

  Photolysis of 3,3′-diamino-2,2′-bi-1,4-naphthoquinonyl

  摘要：

  Pyrex filtered sunlight irradiation of an acetic anhydride of 3,3'-diamino-2,2'-bi-1,4-napthoquinonyl unexpectedly led to the formation of 3',3':N,N-bi[3-amino-2,2'-bi-1,4-napthoquinonyl] which contains only two secondary amino groups. The structure of the photoproduct was elucidated from a FAB mass spectrometric as well as H-1 and C-13 n.m.r. study.

  DOI：

  10.1016/s0040-4020(01)96178-2