bis(N-(n-hexyl)-2-oxy-4-(1-naphtoyloxy)benzaldiminato)copper(II) | 167102-19-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: bis(N-(n-hexyl)-2-oxy-4-(1-naphtoyloxy)benzaldiminato)copper(II)
• CAS: 167102-19-4
• 化学式: C₄₈H₄₈CuN₂O₆
• 分子量: 812.465
• InChiKey: HDRDTTUUWCWOIN-NMVYOYMWSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  1,3,5-三硝基苯 、 bis(N-(n-hexyl)-2-oxy-4-(1-naphtoyloxy)benzaldiminato)copper(II) 以 二氯甲烷 、 丙酮 为溶剂， 以40%的产率得到bis(N-(n-hexyl)-2-oxy-4-(1-naphtoyloxy)benzaldiminato)copper(II)*4(1,3,5-trinitrobenzene)
  参考文献：
  名称：

  The 1:2 and 1:4 π-π type molecular adducts of bis(N-alkyl-2-oxy-4-(1-naphthoyloxy)benzaldiminato)copper(II) and 1,3,5-trinitrobenzene

  摘要：

  Bis(N-alkyl-2-oxy-4-(1-naphthoyloxy)benzaldiminato)copper(II) ([Cu(L(R))(2)]; R=n-C3H7, n-C4H9, n-C5H11, n-C6H13) and 1,3,5-trinitrobenzene (tnb) formed the 1:2 and 1:4 pi-pi type molecular adducts depending on the chain length of the alkyl group, in which parent complexes with the shorter alkyl group (n-C3H7, n-C4H9) gave the 1:2 adducts, while those with the longer a alkyl group (n-C5H11, n-C6H13) gave the 1:4 adducts. One of the 1:4 adducts [Cu(L(R))(2)]. 4tnb (R=n-C6H13) and the parent complex have been subjected to the single-crystal X-ray diffraction method. Both complexes crystallized in the triclinic space group P $($) over bar$$ 1 and each of the copper atoms is positioned at the inversion center. The crystal structure of the 1:4 adduct consists of two kinds of pi-pi type donor-acceptor stacking along the c-axis, where the first stacking is formed between the naphthalene moiety of the complex and one of two tnb molecules and the second stacking is formed between the benzene moiety and the other tnb molecule.

  DOI：

  10.1016/0020-1693(95)04490-z
• 作为产物：
  描述：

  2-hydroxy-4-(1-naphtoyloxy)benzaldehyde 以 甲醇 、 正己烷 、 二氯甲烷 、 氯仿 为溶剂， 生成 bis(N-(n-hexyl)-2-oxy-4-(1-naphtoyloxy)benzaldiminato)copper(II)
  参考文献：
  名称：

  The 1:2 and 1:4 π-π type molecular adducts of bis(N-alkyl-2-oxy-4-(1-naphthoyloxy)benzaldiminato)copper(II) and 1,3,5-trinitrobenzene

  摘要：

  Bis(N-alkyl-2-oxy-4-(1-naphthoyloxy)benzaldiminato)copper(II) ([Cu(L(R))(2)]; R=n-C3H7, n-C4H9, n-C5H11, n-C6H13) and 1,3,5-trinitrobenzene (tnb) formed the 1:2 and 1:4 pi-pi type molecular adducts depending on the chain length of the alkyl group, in which parent complexes with the shorter alkyl group (n-C3H7, n-C4H9) gave the 1:2 adducts, while those with the longer a alkyl group (n-C5H11, n-C6H13) gave the 1:4 adducts. One of the 1:4 adducts [Cu(L(R))(2)]. 4tnb (R=n-C6H13) and the parent complex have been subjected to the single-crystal X-ray diffraction method. Both complexes crystallized in the triclinic space group P $($) over bar$$ 1 and each of the copper atoms is positioned at the inversion center. The crystal structure of the 1:4 adduct consists of two kinds of pi-pi type donor-acceptor stacking along the c-axis, where the first stacking is formed between the naphthalene moiety of the complex and one of two tnb molecules and the second stacking is formed between the benzene moiety and the other tnb molecule.

  DOI：

  10.1016/0020-1693(95)04490-z