S-ethyl-N-diethylamidophosphorous acid chloride | 80797-37-1

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机硫代磷化合物
• 英文名称: S-ethyl-N-diethylamidophosphorous acid chloride
• 英文别名: ethyl diethylphosphoramidochloridothioite；N-[chloro(ethylsulfanyl)phosphanyl]-N-ethylethanamine
• CAS: 80797-37-1
• 化学式: C₆H₁₅ClNPS
• 分子量: 199.685
• InChiKey: NTRBCNVMNCNJPR-UHFFFAOYSA-N

物化性质

• 沸点：
  52-53 °C(Press: 0.02 Torr)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  28.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  S,S-diethyl-N-diethylamidodithiophosphite 在 四氯化碳 、 zinc(II) chloride 作用下， 反应 2.0h， 以2.97 g的产率得到S-ethyl-N-diethylamidophosphorous acid chloride
  参考文献：
  名称：

  Sinyashin, O.G.; Karimullin, Sh. A.; Kostin, V. P., Journal of general chemistry of the USSR, 1986, vol. 56, p. 1505 - 1511

  摘要：

  DOI：

文献信息

• Sinyashin, O. G.; Ofitserov, E. N.; Batyeva, E. S., Journal of general chemistry of the USSR, 1981, p. 2078 - 2080
  作者：Sinyashin, O. G.、Ofitserov, E. N.、Batyeva, E. S.、Pudovik, A. N.

  DOI：——

  日期：——
• AN NMR STUDY OF THE REACTIONS OF CHLOROPHOSPHINES WITH AlC1₃. PHOSPHENIUM CATIONS FEATURING A S-P-N LINKAGE
  作者：Tian-Bao Huang、Ling-Fei Liu、Jing-Ling Zhang、Xuang-Long Xu、Wen-Fang Huang、Ru-Yu Chen、Ke Wang、Xiao-Ming Yu、Xiao-Peng Liu

  DOI：10.1080/10426509808035742

  日期：1998.9.1

  The N-P+-S phosphenium cations 1, 2 and 3 have been prepared by treatment of the respective precursor chlorophosphines 4, 5 and 6 with the stoichiometric quantity of AlCl3 in CH2Cl2 solution. The cations 3 are noteworthy that they are the first aliphatic phosphenium cations featuring a P-S bond. That the values of P-31 chemical shifts of phosphenium cations 3 are larger than those of aliphatic N-P+-N and N-P+-Cl cations characterize a relative inferior it-donor ability of RS group to R2N group and to Cl. The exo conformation of group at sulfur to dialkylamino group in 3 is proposed on the rare steric effect on P-31 chemical shifts of substitutes at sulfur.
• Kostin, V. P.; Sinyashin, O. G.; Batyeva, E. S., Journal of general chemistry of the USSR, 1985, vol. 55, # 5, p. 1055 - 1056
  作者：Kostin, V. P.、Sinyashin, O. G.、Batyeva, E. S.、Pudovik, A. N.

  DOI：——

  日期：——
• SINYASHIN, O. G.;OFITSEROV, E. N.;BATYEVA, EH. S.;PUDOVIK, A. N., ZH. OBSHCH. XIMII, 1981, 51, N 11, 2410-2413
  作者：SINYASHIN, O. G.、OFITSEROV, E. N.、BATYEVA, EH. S.、PUDOVIK, A. N.

  DOI：——

  日期：——
• SINYASHIN, O. G.;KARIMULLIN, SH. A.;KOSTIN, V. P.;BATYEVA, EH. S.;PUDOVIK+, ZH. OBSHCH. XIMII, 1986, 56, N 8, 1700-1707
  作者：SINYASHIN, O. G.、KARIMULLIN, SH. A.、KOSTIN, V. P.、BATYEVA, EH. S.、PUDOVIK+

  DOI：——

  日期：——