| 99708-75-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• CAS: 99708-75-5
• 化学式: C₁₄H₃₄NP₂Pt
• 分子量: 473.458
• InChiKey: QIFGSXVLDDXYDM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  trans diiodobis(triethylphosphine)platinum(II) 、 乙腈 在 sodium perchlorate 作用下， 以 乙腈 、 苯 为溶剂， 生成
  参考文献：
  名称：

  Electrochemical synthesis and spectroscopic characterization of a mercury–platinum–hydride complex

  摘要：

  Controlled potential bulk reductive electrolysis of trans-[PtI2(PEt3)(2)] in 5:2 C6H5CN:C6H6 (saturated with NaClO4)at a Hg pool electrode at -1.5 V (vs. Ag/AgCl) and at approximately 0 degrees C, yielded two compounds detectable by P-31{H-1} NMR spectroscopy. One compound was the starting material, trans-[PtI2(PEt3)(2)], while the other displayed a complex spectrum. Analysis of the H-1, P-31{H-1} and Pt-195{H-1} NMR spectra suggested that the compound contained an unaccounted for spin one-half nucleus. Scanning electron microscopy-energy dispersive spectroscopy and inductively coupled plasma atomic emission spectroscopy indicated that the compound contained mercury and the spectra could be satisfactorily interpreted in terms of a mercury-platinum-hydride structure. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00023-2