1,6-diphenylhexane-1,6-diamine | 58819-33-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,6-diphenylhexane-1,6-diamine
• 英文别名: 1,6-diphenyl-hexanediyldiamine；1,6-Diphenyl-hexandiyldiamin；α.ζ-Diamino-α.ζ-diphenyl-hexan
• CAS: 58819-33-3
• 化学式: C₁₈H₂₄N₂
• 分子量: 268.402
• InChiKey: NXORCMNHLWPGPV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  20
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,6-diphenylhexane-1,6-diamine 生成 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Borsche; Wollemann, Chemische Berichte, 1912, vol. 45, p. 3717

  摘要：

  DOI：
• 作为产物：
  描述：

  1,4-二苯甲酰丁烷 在 titanium(IV) isopropylate 、 氨 、 sodium tetrahydroborate 作用下， 以 乙醇 为溶剂， 以20%的产率得到1,6-diphenylhexane-1,6-diamine
  参考文献：
  名称：

  LIGAND COMPOUND, ORGANIC CHROMIUM COMPOUND, CATALYST SYSTEM FOR OLIGOMERIZATION OF OLEFINS, AND METHOD FOR OLIGOMERIZATION OF OLEFINS USING THE CATALYST SYSTEM (AS AMENDED)

  摘要：

  本发明涉及配体化合物、烯烃寡聚催化体系以及使用该催化体系进行烯烃寡聚的方法。本发明的烯烃寡聚催化体系不仅具有优异的催化活性，而且对1-己烯或1-辛烯表现出高选择性，从而能够更有效地制备α-烯烃。

  公开号：

  US20170029346A1

文献信息

• Alkylenepoly(aralkylamines) and the salts thereof
  申请人：ENDO LABORATORIES INC.

  公开号：US03929887A1

  公开（公告）日：1975-12-30

  Novel alkylenepoly(aralkylamines) and related compounds, the pharmaceutically acceptable acid addition salts thereof and compositions containing such substances have been found to exhibit high sustained and useful levels of fibrinolytic acitivity in mammals.

  新型的烷基聚（芳基胺）和相关化合物，其药学上可接受的酸盐加成物以及含有这些物质的组合物已被发现在哺乳动物中表现出高持续和有用的纤溶活性。
• LIGAND COMPOUND, ORGANIC CHROME COMPOUND, CATALYST SYSTEM FOR OLEFIN OLIGOMERIZATION, AND METHOD FOR OLIGOMERIZING OLEFIN USING SAME
  申请人：LG Chem, Ltd.

  公开号：EP3101039A1

  公开（公告）日：2016-12-07

  The present invention relates to a ligand compound, a catalyst system for oligomerization of olefins, and a method for oligomerization of olefins using the catalyst system. The catalyst system for oligomerization of olefins according to the present invention not only has excellent catalytic activity, but also exhibits high selectivity to 1-hexene or 1-octene, thus enabling more efficient preparation of alpha-olefin.

  本发明涉及一种配体化合物、一种用于烯烃低聚的催化剂体系以及一种使用该催化剂体系进行烯烃低聚的方法。根据本发明的烯烃低聚催化剂体系不仅具有优异的催化活性，而且对 1-己烯或 1-辛烯具有高选择性，从而能够更高效地制备α-烯烃。
• CATALYST SYSTEM FOR OLEFIN OLIGOMERIZATION, AND METHOD FOR OLIGOMERIZING OLEFINS BY USING SAME
  申请人：LG Chem, Ltd.

  公开号：EP3260475A1

  公开（公告）日：2017-12-27

  The present invention relates to a catalyst system for olefin oligomerization and a method for olefin oligomerization, and more specifically, a catalyst system for olefin oligomerization and a method for olefin oligomerization that have more improved supporting efficiency due to a ligand compound capable of functioning as a tether to a support, and thus, exhibit high activity in the olefin oligomerization even with smaller amounts of catalyst composition and cocatalyst, thus enabling more efficient preparation of alpha-olefins.

  本发明涉及一种用于烯烃低聚的催化剂体系和一种用于烯烃低聚的方法，更具体地说，是一种用于烯烃低聚的催化剂体系和一种用于烯烃低聚的方法，该催化剂体系和方法中的配体化合物能够作为与载体的系链发挥作用，因而具有更高的支撑效率，即使使用较少量的催化剂组合物和助催化剂，也能在烯烃低聚过程中表现出较高的活性，从而能够更高效地制备α-烯烃。
• Catalyst system for olefin oligomerization and method for olefin oligomerization using the same
  申请人：LG CHEM, LTD.

  公开号：US10427991B2

  公开（公告）日：2019-10-01

  The present invention relates to a catalyst system for olefin oligomerization and a method for olefin oligomerization, and more specifically, a catalyst system for olefin oligomerization and a method for olefin oligomerization that have more improved supporting efficiency due to a ligand compound capable of functioning as a tether to a support, and thus, exhibit high activity in the olefin oligomerization even with smaller amounts of catalyst composition and cocatalyst, thus enabling more efficient preparation of alpha-olefins.

  本发明涉及一种用于烯烃低聚的催化剂体系和一种用于烯烃低聚的方法，更具体地说，是一种用于烯烃低聚的催化剂体系和一种用于烯烃低聚的方法，该催化剂体系和方法中的配体化合物能够作为与载体的系链发挥作用，因而具有更高的支撑效率，即使使用较少量的催化剂组合物和助催化剂，也能在烯烃低聚过程中表现出较高的活性，从而能够更高效地制备α-烯烃。
• Ligand compound, organic chromium compound, catalyst system for oligomerization of olefins, and method for oligomerization of olefins using the catalyst system
  申请人：LG CHEM, LTD.

  公开号：US10472302B2

  公开（公告）日：2019-11-12

  The present invention relates to a ligand compound, a catalyst system for oligomerization of olefins, and a method for oligomerization of olefins using the catalyst system. The catalyst system for oligomerization of olefins according to the present invention not only has excellent catalytic activity, but also exhibits high selectivity to 1-hexene or 1-octene, thus enabling more efficient preparation of alpha-olefin.

  本发明涉及一种配体化合物、一种用于烯烃低聚的催化剂体系以及一种使用该催化剂体系进行烯烃低聚的方法。根据本发明的烯烃低聚催化剂体系不仅具有优异的催化活性，而且对 1-己烯或 1-辛烯具有高选择性，从而能够更高效地制备α-烯烃。