trans-[Pd(C8H6N)2(PEt3)2] | 505027-28-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: trans-[Pd(C8H6N)2(PEt3)2]
• 英文别名: indol-1-ide;palladium(2+);triethylphosphane
• CAS: 505027-28-1
• 化学式: C₂₈H₄₂N₂P₂Pd
• 分子量: 575.022
• InChiKey: MTXFCPIHRHAXOJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  吲哚 、 tris(triethylphosphine)ppalladium(0) 以 甲苯 为溶剂， 以70%的产率得到trans-[Pd(C8H6N)2(PEt3)2]
  参考文献：
  名称：

  Oxidative insertion into the N–H bond of carbazole, indole and pyrrole with zerovalent metals

  摘要：

  The reactions of carbazole (C12H8NH), indole (C8H6NH) and pyrrole (C4H4NH) with the zerovalent [Pt(PEt3)(3)], [Pd(PEt3)(3)] and [Ni(PEt3)(3)] gave oxidative insertion into the N-H bond, affording the corresponding hydrides of the type trans-[HM(LN)(PEt3)(2)], LN = de-protonated heterocyclic ligand; the isolated compounds for platinum were trans-[HPt(C8H6N)(PEt3)(2)] (1), trans-[HPt(C4H4N)(PEt3)(2)] (2), and for nickel trans-[HNi(C12H8N)(PEt3)(2)] (3), trans-[HNi(C8H6N)(PEt3)(2)] (4) and trans-[HNi(C4H4N)(PEt3)(2)] (5); on using palladium the corresponding hydrides were also detected in solution, however, after longer reaction time the double substituted compounds: trans-[Pd(C12H8N)(2)(PEt3)(2)] (6), trans-[Pd(C8H6N)(2)(PEt3)(2)] (7) and trans-[Pd(C4H4N)(2)(PEt3)(2)] (8) were obtained. A crystal structure is reported for 6. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01979-4