azidobis[3-(dimethylamino)propyl]aluminium | 185536-86-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: azidobis[3-(dimethylamino)propyl]aluminium
• 英文别名: aluminum;N,N-dimethylpropan-1-amine;azide
• CAS: 185536-86-1
• 化学式: C₁₀H₂₄AlN₅
• 分子量: 241.316
• InChiKey: QCABXIFJJZNLKY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  AlCl₂(DMP) 、 sodium azide 以 not given 为溶剂， 生成 azidobis[3-(dimethylamino)propyl]aluminium
  参考文献：
  名称：

  Structures of (C₅H₅N)₃Al(N₃)₃, [Me₂N(CH₂)₃]₂Al(N₃) and Me₂(N₃)Al(H₂NBu^t). Low-temperature OMVPE of AlN in the absence of ammonia

  摘要：

  New Lewis-base stabilized monomeric azido alanes are synthesized by salt metathesis from the corresponding chloro alanes and an excess of sodium azide; thin films of crystalline AlN are grown by OMVPE at 400-850 degrees C in vacuo.

  DOI：

  10.1039/cc9960002685

文献信息

• Syntheses and Structures of Intramolecularly Coordinated Azidoalanes
  作者：Jens Müller、Roland A. Fischer、Harald Sussek、Peter Pilgram、Ruimin Wang、Hans Pritzkow、Eberhard Herdtweck

  DOI：10.1021/om9706875

  日期：1998.1.1

  The four intramolecularly coordinated azidoalanes R2Al(N-3) and RAltBu(N-3) (R = (CH2)(3)NMe2 (1b, 3b), 2-(Me2NCH2)C6H4 (2b, 4b)) were synthesized by reaction of the corresponding aluminum chlorides (1a-4a) with an excess of dry sodium azide in refluxing toluene or toluene/THF. The structures of the products were deduced from H-1, C-13, and Al-27 NMR spectra and were confirmed by X-ray structural determinations of la, Ib, and 2b. The compounds of type 1 and 2 contain pentacoordinated Al atoms, whereas the alanes of type 3 and 4 show tetracoordination of the central Al atoms.