N21-benzyl-N23-(naphth-2-ylmethyl)-5,10,15,20-tetrakis(di-tert-butyl-4-oxocyclohexa-2,5-dienyl)porphyrinogen | 1229404-26-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: N21-benzyl-N23-(naphth-2-ylmethyl)-5,10,15,20-tetrakis(di-tert-butyl-4-oxocyclohexa-2,5-dienyl)porphyrinogen
• CAS: 1229404-26-5
• 化学式: C₉₄H₁₀₆N₄O₄
• 分子量: 1355.9
• InChiKey: OYEAFDLOXUYPIW-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  N21-benzyl-N23-(naphth-2-ylmethyl)-5,10,15,20-tetrakis(di-tert-butyl-4-oxocyclohexa-2,5-dienyl)porphyrinogen 、 对溴溴苄 、 对硝基溴化苄 在 potassium carbonate 作用下， 以 乙醇 为溶剂， 生成 4-[21-Benzyl-24-[(4-bromophenyl)methyl]-10,15,20-tris(3,5-ditert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)-23-(naphthalen-2-ylmethyl)-22-[(4-nitrophenyl)methyl]porphyrin-5-ylidene]-2,6-ditert-butylcyclohexa-2,5-dien-1-one
  参考文献：
  名称：

  Stable pseudotetrahedral supermolecules based on an oxoporphyrinogen

  摘要：

  Topologically asymmetric compounds, important as chiral nanoscale building blocks, were synthesized using stepwise N-alkylation on tetrakis(3,5-di-t-butyl-4-oxocyclohexadien-2,5-yl) porphyrinogen as revealed by X-ray crystallographic studies on a porphyrinogen molecule bearing four different N-substituents. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.03.113
• 作为产物：
  描述：

  5,10,15,20-tetrakis(3,5-di-tert-butyl-4-oxocyclohexa-2,5-dienylidene)-N²¹-(naphth-2-ylmethyl)porphyrinogen 、 溴甲苯 在 potassium carbonate 作用下， 以 乙醇 为溶剂， 生成 N21-benzyl-N23-(naphth-2-ylmethyl)-5,10,15,20-tetrakis(di-tert-butyl-4-oxocyclohexa-2,5-dienyl)porphyrinogen
  参考文献：
  名称：

  Stable pseudotetrahedral supermolecules based on an oxoporphyrinogen

  摘要：

  Topologically asymmetric compounds, important as chiral nanoscale building blocks, were synthesized using stepwise N-alkylation on tetrakis(3,5-di-t-butyl-4-oxocyclohexadien-2,5-yl) porphyrinogen as revealed by X-ray crystallographic studies on a porphyrinogen molecule bearing four different N-substituents. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.03.113