di(thiocyanato-N)diaqua(2,6-bis(benzimidazole-2'-yl)pyridine)nickel(II) | 590369-36-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: di(thiocyanato-N)diaqua(2,6-bis(benzimidazole-2'-yl)pyridine)nickel(II)
• 英文别名: 2-[6-(1H-benzimidazol-2-yl)pyridin-2-yl]-1H-benzimidazole;nickel(2+);diisothiocyanate;dihydrate
• CAS: 590369-36-1
• 化学式: C₂₁H₁₇N₇NiO₂S₂
• 分子量: 522.234
• InChiKey: PRTAPSZLMWUKMW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  水 、 2,6-双(2-苯并咪唑基)吡啶 、 nickel(II) thiocyanate 以 乙醇 为溶剂， 以70%的产率得到di(thiocyanato-N)diaqua(2,6-bis(benzimidazole-2'-yl)pyridine)nickel(II)
  参考文献：
  名称：

  Metal Thiocyanato Complexes: Synthesis, Magnetic, and Spectral Studies of Some Mixed‐Ligand Thiocyanato Complexes of Nickel(II) Involving Benzothiazole and Benzimidazole Derivatives

  摘要：

  A new series of mixed-ligand thiocyanato complexes of nickel(II) of the compositions [Ni(NCS)(2)(L)(4)], where L = 2-mercaptobenzothiazole (2-MBZT), 2-(2'-hydroxyphenyl)-benzothiazole (2'-HPBZT), 2-(2'-tolyl)benzothiazole (2'-TOBZT), 2-(3'-tolyl)benzothiazole (3'-TOBZT), [Ni(NCS)(2)(2-AMBZT)(2)] and [Ni(NCS)(2)(BBZLY)(H2O)(2)], where 2-AMBZT = 2-aminobenzothiazole and BBZLPY = 2,6-bis(benzimidazole-2'-yl)pyridine, has been synthesized by the interaction of nickel(II) thiocyanate with the respective ligands. The compounds so obtained were characterized by analytical data, molar conductances, magnetic measurements, infrared and electronic spectral studies. Suitable octahedral structures have been suggested for these complexes.

  DOI：

  10.1081/sim-120019992