nitrosocyclododecane | 46348-04-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: nitrosocyclododecane
• 英文别名: Dimeres Nitrosocyclododecan
• CAS: 46348-04-3
• 化学式: C₁₂H₂₃NO
• 分子量: 197.321
• InChiKey: RGSLPQBXVOKMLZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  29.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  nitrosocyclododecane 在 Lindlar's catalyst 氢气 作用下， 生成 N-Cyclododecyl-cyclododecanonimin
  参考文献：
  名称：

  Meister,H., Justus Liebigs Annalen der Chemie, 1964, vol. 679, p. 83 - 94

  摘要：

  DOI：
• 作为产物：
  描述：

  Cyclododecylhydroxylamin 在 Co catalyst 氧气 作用下， 生成 nitrosocyclododecane
  参考文献：
  名称：

  Meister,H., Justus Liebigs Annalen der Chemie, 1964, vol. 679, p. 83 - 94

  摘要：

  DOI：

文献信息

• Iron(III) Complex Catalyzed Nitrosation of Terminal and 1,2-Disubstituted Olefins with Butyl Nitrite and Phenylsilane
  作者：Koji Kato、Teruaki Mukaiyama

  DOI：10.1246/cl.1992.1137

  日期：1992.7

  In the presence of a catalytic amount of tris(1,3-diketonato)iron(III) complex, various terminal and 1,2-disubstituted olefins are converted into the corresponding nitroso alkane dimers in fairly good yields on treatment with phenylsilane and butyl nitrite at room temperature.

  在催化量的三(1,3-二酮基)铁(III)复合物存在下，各种末端和1,2-二取代烯烃在室温下与苯基硅烷和丁基亚硝酸盐反应，转化为相应的亚硝基烷基二聚体，产率相当不错。
• METHOD FOR PRODUCING LACTAM COMPOUND
  申请人：Shibamoto Akihiro

  公开号：US20100029931A1

  公开（公告）日：2010-02-04

  Disclosed is a method for industrially efficiently producing a lactam compound having 8 to 15 carbon atoms at low cost by allowing a rearrangement reaction of a cyclic oxime compound to proceed without causing large amounts of by-products such as ammonium sulfate. [Solving Means] Disclosed is a method for producing a lactam compound, which includes the step of rearranging a cyclic oxime compound in a nonpolar solvent B in the presence of an aromatic compound A to give the lactam compound, in which the aromatic compound A has a leaving group bonded to a carbon atom constituting its aromatic ring and contains, as an atom constituting the aromatic ring, a heteroatom, or a carbon atom bonded with an electron-withdrawing group, the cyclic oxime compound is represented by following Formula (1): wherein “m” denotes an integer of 7 to 14, and the lactam compound is represented by following Formula (2): wherein “m” is as defined above.

  揭示了一种工业高效地以低成本生产具有8至15个碳原子的内酰胺化合物的方法，通过使环氧肟化合物的重排反应在不产生大量副产物如硫酸铵的情况下进行。 【解决手段】揭示了一种生产内酰胺化合物的方法，包括在非极性溶剂B中在芳香化合物A存在下重排环氧肟化合物的步骤，以得到内酰胺化合物，其中芳香化合物A具有与构成其芳香环的碳原子结合的离去基团，并且包含作为构成芳香环的原子，一个杂原子，或者与带有电子吸引基团的碳原子结合，环氧肟化合物由以下式（1）表示：其中“m”表示一个整数，范围为7至14，内酰胺化合物由以下式（2）表示：其中“m”如上所定义。
• METHOD FOR PRODUCING C4-C15 LACTAMS
  申请人：BASF SE

  公开号：US20190040005A1

  公开（公告）日：2019-02-07

  The present invention relates to a process for preparing C 4 -C 15 lactams, in which a C 1 -C 10 -alkyl nitrite is reacted with a C 4 -C 15 -cycloalkane and is illuminated with a light-emitting diode during the reaction. This forms a C 4 -C 15 -cyclohexanone oxime which is then converted further to a C 4 -C 15 lactam; the C 1 -C 10 alcohol formed is recycled into the preparation of the C 1 -C 10 -alkyl nitrite.

  本发明涉及一种制备C4-C15内酰胺的方法，其中将C1-C10烷基亚硝酸酯与C4-C15环烷烃反应，并在反应过程中照射LED光。这样形成了C4-C15环己酮肟，然后进一步转化为C4-C15内酰胺；生成的C1-C10醇被回收再用于制备C1-C10烷基亚硝酸酯。
• Process for producing organic compounds using nitrites
  申请人：——

  公开号：US20030171618A1

  公开（公告）日：2003-09-11

  A process produces an organic compound by allowing (A) a compound capable of generating a free radical to react with (B) at least one of esters and salts of nitrous acid in the presence of a nitrogen-containing cyclic compound constitutively having a skeleton represented by following Formula (i) in its ring: 1 wherein X is an oxygen atom or an —OR group, and wherein R is a hydrogen atom or a hydroxyl-protecting group. Examples of the nitrogen-containing cyclic compound are cyclic imide compounds having a cyclic imide skeleton represented by following Formula (I): 2 wherein n is 0 or 1; X is an oxygen atom or an —OR group, and wherein R is a hydrogen atom or a hydroxyl-protecting group.

  一种过程通过在氮含环状化合物的存在下，使得(A)能产生自由基的化合物与(B)亚硝酸酯和盐中的至少一种反应，从而产生一种有机化合物。该氮含环状化合物的骨架由以下式子（i）中的环所表示：1其中X是氧原子或-OR基团，R是氢原子或羟基保护基团。氮含环状化合物的例子是具有以下式子（I）中的环状咪唑酮骨架的环状咪唑酮化合物：2其中n为0或1；X是氧原子或-OR基团，R是氢原子或羟基保护基团。
• Method for producing C4-C15 lactams
  申请人：BASF SE

  公开号：US10618873B2

  公开（公告）日：2020-04-14

  The present invention relates to a process for preparing C4-C15 lactams, in which a C1-C10-alkyl nitrite is reacted with a C4-C15-cycloalkane and is illuminated with a light-emitting diode during the reaction. This forms a C4-C15-cyclohexanone oxime which is then converted further to a C4-C15 lactam; the C1-C10 alcohol formed is recycled into the preparation of the C1-C10-alkyl nitrite.

  本发明涉及一种制备 C4-C15 内酰胺的工艺，其中 C1-C10 烷基亚硝酸盐与 C4-C15 环烷反应，并在反应过程中用发光二极管照射。由此形成 C4-C15 环己酮肟，然后进一步转化为 C4-C15 内酰胺；形成的 C1-C10 醇被回收用于制备 C1-C10 烷基亚硝酸盐。