| 1580000-10-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• CAS: 1580000-10-7
• 化学式: C₈₇H₁₁₇BrN₈O₁₂S₆Zn
• 分子量: 1804.62
• InChiKey: TZMRTUBYYYKTMI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 sodium azide 、 四溴化碳 作用下， 以 四氢呋喃 、 水 为溶剂， 反应 4.0h， 以75%的产率得到
  参考文献：
  名称：

  Electron-Donating Behavior of Few-Layer Graphene in Covalent Ensembles with Electron-Accepting Phthalocyanines

  摘要：

  We describe herein the first example of highly exfoliated graphene covalently linked to electron accepting phthalocyanines. The functionalization of the nanocarbon surface with alkylsulfonyl phthalocyanines was attained by means of a "click" chemistry protocol. The new ensemble was fully characterized (thermogravimetric analysis, atomic force microscopy, transmission electron microscopy and Raman, as well as ground-state absorption) and was studied in terms of electron donor-acceptor interactions in the ground and in the excited state. In particular, a series of steady-state and time-resolved spectroscopy experiments demonstrated photoinduced electron transfer from the graphene to the electron-accepting phthalocyanines. This is the first example of an electron dono-acceptor nanoconjugate, that is, few-layer graphene/phthalocyanine, pinpointing the uncommon electron donating character of graphene.

  DOI：

  10.1021/ja411830x
• 作为产物：
  描述：

  在 四溴化碳 、 三苯基膦 作用下， 以 二氯甲烷 为溶剂， 反应 24.0h， 以70%的产率得到
  参考文献：
  名称：

  Electron-Donating Behavior of Few-Layer Graphene in Covalent Ensembles with Electron-Accepting Phthalocyanines

  摘要：

  We describe herein the first example of highly exfoliated graphene covalently linked to electron accepting phthalocyanines. The functionalization of the nanocarbon surface with alkylsulfonyl phthalocyanines was attained by means of a "click" chemistry protocol. The new ensemble was fully characterized (thermogravimetric analysis, atomic force microscopy, transmission electron microscopy and Raman, as well as ground-state absorption) and was studied in terms of electron donor-acceptor interactions in the ground and in the excited state. In particular, a series of steady-state and time-resolved spectroscopy experiments demonstrated photoinduced electron transfer from the graphene to the electron-accepting phthalocyanines. This is the first example of an electron dono-acceptor nanoconjugate, that is, few-layer graphene/phthalocyanine, pinpointing the uncommon electron donating character of graphene.

  DOI：

  10.1021/ja411830x