azacyclopentadecan-2-one | 52262-71-2

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 大环内酰胺类
• 英文名称: azacyclopentadecan-2-one
• 英文别名: Azacyclopentadecan-2-on；1-Aza-2-cyclopentadecanon；Azacyclopentadecan-15-one
• CAS: 52262-71-2
• 化学式: C₁₄H₂₇NO
• 分子量: 225.374
• InChiKey: PUFNIVXNEBWJIJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.93
• 拓扑面积：
  29.1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  azacyclopentadecan-2-one 在 吡啶 、 dinitrogen tetraoxide 作用下， 以 四氯化碳 为溶剂， 反应 7.0h， 生成 1-氧杂环十五烷-2-酮
  参考文献：
  名称：

  内酰胺的N-亚硝化和N-硝化。从大内酰胺到大内酯

  摘要：

  内酰胺的N-亚硝基和N-硝基衍生物，从2-吡咯烷酮到15-十五烷内酰胺，已通过1 H NMR，13 c NMR和IR光谱进行了表征。这些亚硝基内酰胺和硝基内酰胺向内酯的转化已得到系统地（重新）研究。

  DOI：

  10.1016/0040-4020(89)80118-8
• 作为产物：
  描述：

  cyclotetradecanone oxime 在 硫酸 、 水 作用下， 生成 azacyclopentadecan-2-one
  参考文献：
  名称：

  Ruzicka et al., Helvetica Chimica Acta, 1949, vol. 32, p. 552

  摘要：

  DOI：

文献信息

• TORRA, NURIA;URPI, FELIX;VILARRASA, JAUME, TETRAHEDRON, 45,(1989) N, C. 863-868
  作者：TORRA, NURIA、URPI, FELIX、VILARRASA, JAUME

  DOI：——

  日期：——
• SAFETY EQUIPMENT TO PROTECT A WEARER COMPRISING AN AROMATIC POLYAMIDE COMPOSITION, AND AROMATIC POLYAMIDE COMPOSITION SUITABLE FOR MAKING SAID SAFETY EQUIPMENT
  申请人：Solvay Advanced Polymers, L.L.C.

  公开号：EP1720616A1

  公开（公告）日：2006-11-15
• Method for the Production of an Aqueous Polymer Dispersion
  申请人：Kong Xiang-Ming

  公开号：US20080132674A1

  公开（公告）日：2008-06-05

  A process for preparing an aqueous polymer dispersion, in which, in an aqueous medium, in a first reaction stage, an aminocarboxylic acid compound is reacted in the presence of a hydrolase and of a dispersant, and, if appropriate, of an ethylenically unsaturated monomer and/or of a low water solubility organic solvent to give a polyamide and thereafter, in the presence of the polyamide, in a second reaction stage an ethylenically unsaturated monomer is free-radically polymerized.
• Method for Producing an Aqueous Polyamide Dispersion
  申请人：Kong Xiang-Ming

  公开号：US20080167418A1

  公开（公告）日：2008-07-10

  A process for preparing an aqueous polyamide dispersion by hydrolase-catalyzed reaction of an aminocarboxylic acid compound in aqueous medium.
• PROCESS FOR PREPARING POLYMERS FILLED WITH NANOSCALE METAL OXIDES
  申请人：Karpov Andrey

  公开号：US20100036052A1

  公开（公告）日：2010-02-11

  A process is proposed for preparing polymers filled with nanoscale metal oxides and comprises the following steps: a) preparing a nanosuspension of one or more crystalline metal oxides, hydroxides or oxide hydroxides by heating a suspension of one or more compounds comprising the corresponding metals in a first polymerizable compound to a temperature greater than the boiling point of water under process pressure and less than the boiling temperature of the first polymerizable compound and also less than the temperature at which the polymerization of the first polymerizable compound commences, in the presence of water in an amount corresponding to 1 to 10 oxygen atoms per metal atom of the compound or compounds comprising the corresponding metals, and b) polymerizing the first polymerizable compound under pressure and temperature conditions typical for the first polymerizable compound.