(Cl2 B N P Cl2 N P Cl3)2 | 478157-32-3

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 其他非金属卤化物
• 英文名称: (Cl2 B N P Cl2 N P Cl3)2
• 英文别名: trichloro-[dichloro-[2,2,4,4-tetrachloro-3-[dichloro-[(trichloro-λ5-phosphanylidene)amino]-λ5-phosphanylidene]-1,3-diazonia-2,4-diboranuidacyclobut-1-ylidene]-λ5-phosphanyl]imino-λ5-phosphane
• CAS: 478157-32-3
• 化学式: B₂Cl₁₄N₄P₄
• 分子量: 697.886
• InChiKey: PVFFNHMSZAUIMO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.02
• 重原子数：
  24
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  30.7
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  trichloro(trimethylsilyl)phosphoranimine 、 三氯化硼 以 二氯甲烷 为溶剂， 以73%的产率得到(Cl2 B N P Cl2 N P Cl3)2
  参考文献：
  名称：

  膦亚氨基配合物 [Cl2BNPCl2NPCl3]2 和 [Br2BNPCl3]2 的合成、晶体结构和光谱表征

  摘要：

  The phosphorane iminato complexes have been obtained as white crystalline powders at reacting Me3SiNPCl3 with BCl3, and BBr3, respectively. Crystallization from CH2Cl2 yields colourless crystals which have been characterized by single crystal X-ray diffraction analyses. [Cl2BNPCl2NPCl3](2) (1) crystallizes in space group P 2(1)/n with a = 961.5(1), b = 830.8(1), c = 1517.0(2) pm, beta = 107.32(1)degrees, Z = 2, R-1 = 0.0479. The molecule is centrosymmetric, and shows a square planar B2N2 four-membered ring with B-N distances of 154.3 pm. [Br2BNPCl3](2) (2) crystallizes in space group Cmca with a = 1334,93(8), b = 1189.55(7), c = 1026.42(6) pin, Z = 4, R-1 = 0.0436. The compound forms dimeric molecules with point symmetry C-2h, The characteristic Feature is a planar square B2N2 four-membered ring with B-N distances of 155.4 pm. The compounds have been characterized by NMR-, IR-, and MS-spectroscopy.

  DOI：

  10.1002/1521-3749(200209)628:9/10<2000::aid-zaac2000>3.0.co;2-3