Molybdenum, tris(acetonitrile)trichloro- | 119719-04-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Molybdenum, tris(acetonitrile)trichloro-
• 英文别名: mer-tris(acetonitrile)-trichloromolybdenum
• CAS: 119719-04-9；39194-53-1；45047-76-5
• 化学式: C₆H₉Cl₃MoN₃
• 分子量: 325.457
• InChiKey: YLOPAXHDBYIVID-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Molybdenum, tris(acetonitrile)trichloro- 在 2.4.6-tri-isopropylthiophenol 、 triethylamine 作用下， 以 乙腈 为溶剂， 以51%的产率得到
  参考文献：
  名称：

  乙腈四（2,4,6-三异丙硫基苯酚基）钼（IV）的合成及X射线晶体结构

  摘要：

  [MoCl 3（NCCH 3）3 ]与过量的2,4,6-三异丙基硫代苯酚在乙腈中反应，生成[Mo（SC 6 H 2 Pr i 3 -2,4,6）4（NCCH 3）]钼被氧化的地方。的X射线晶体结构测定表明关于与CH钼三方-双锥3 CN基团占据的顶端部位。

  DOI：

  10.1039/dt9880002535
• 作为产物：
  描述：

  钼,二(乙酰腈)四氯- 在 Sn, 、 acetonitrile 作用下， 以 乙腈 为溶剂， 以90%的产率得到Molybdenum, tris(acetonitrile)trichloro-
  参考文献：
  名称：

  乙腈四（2,4,6-三异丙硫基苯酚基）钼（IV）的合成及X射线晶体结构

  摘要：

  [MoCl 3（NCCH 3）3 ]与过量的2,4,6-三异丙基硫代苯酚在乙腈中反应，生成[Mo（SC 6 H 2 Pr i 3 -2,4,6）4（NCCH 3）]钼被氧化的地方。的X射线晶体结构测定表明关于与CH钼三方-双锥3 CN基团占据的顶端部位。

  DOI：

  10.1039/dt9880002535

文献信息

• The use of (Me₃Si)₂NN(SiMe₃)₂as a reagent for the synthesis of µ-dinitrogen complexes or as a homogeneous one-electron reducing agent
  作者：Jonathan R. Dilworth、Stephen J. Harrison、Richard A. Henderson、David R. M. Walton

  DOI：10.1039/c39840000176

  日期：——

  The reaction of NbCl5 with (Me3Si)2NN(SiMe3)2, in the presence of tetrahydrofuran (thf) gives high yields (ca. 80%) of [NbCl3(thf)2}2N2](A); (A), or its tantalum analogue, reacts with Me3SiS2CNEt2 to give a high yield of the dinitrogen complexes with exclusively sulphur co-ligands [M(S2CNEt2)3}2N2](M = Nb or Ta), and reaction of [MoCl4L2](L = MeCN or thf) with (Me3Si)2NN(SiMe3)2 gives [MoCl3L3] in high yield, together with N2.

  在四氢呋喃（thf）存在下，NbCl5 与 (Me3Si)2NN(SiMe3)2 发生反应，得到高产率（约 80%）的 [NbCl3(thf)2}2N2](A)；80%）的[NbCl3(thf)2}2N2](A)；(A)或其钽类似物与 Me3SiS2CNEt2 反应，可得到高产率的二氮配合物，该配合物的配位体完全为硫[M(S2CNEt2)3}2N2]（M = Nb 或 Ta）；[MoCl4L2]（L = MeCN 或 thf）与 (Me3Si)2NN(SiMe3)2 反应，可得到高产率的[MoCl3L3]和 N2。
• Synthesis and reactivity of molybdenum-sulfur cubes
  作者：C.L. Coyle、K.A. Eriksen、S. Farina、J. Francis、Y. Gea、M.A. Greaney、P.J. Guzi、T.R. Halbert、H.H. Murray、E.I. Stiefel

  DOI：10.1016/s0020-1693(00)92400-9

  日期：1992.8

  A series of tetranuclear Mo4S4(R2NCS2)6 complexes has been prepared by using the 'self-assembly' route as well as by synthesis from well-defined molecular building blocks. A variety of mononuclear, dinuclear and trinuclear building blocks have been successfully used to prepare the tetranuclear Mo4S46+ complexes. These thiocubanes have been prepared with mono-anionic 1,1-dithiolate ligands, which provide each of the Mo atoms with a pseudo-octahedral coordination geometry and result in the formation of neutral species. Mo4S4L6 complexes with dialkyldithiocarbamate (DTC), R2NCS2; dialkyldithiophosphate (DDP), (RO)2PS2; alkylxanthate (XAN), ROCS2; and alkylthioxanthate (THIOXAN), RSCS2 ligands have been prepared. The structure of the Mo4S4(DDP)6 complex was determined by single crystal X-ray structure analysis and is compared with the structures of other known Mo4S4 thiocubane complexes. The synthesis, electrochemistry, reactivity and bonding of the tetranuclear clusters are presented.
• Synthesis and characterization of the molybdenum(IV) oxo-selenolate complex [MoO(Ph2P(O)CH2CH2P(Ph)CH2CH2PPh2)(Se-2,4,6-(CH3)3C6H2)2]
  作者：P.Michael Boorman、Heinz-Bernhard Kraatz、Masood Parvez

  DOI：10.1016/s0277-5387(00)84974-8

  日期：1993.3

  The presence of adventitious oxygen in the reaction of [(Triphos)MoCl3] (Triphos = Ph2PCH2CH2P(Ph)CH2CH2PPh2) with NaSeC6H2Me3-2,4,6 in THF leads to the formation of [fac-MoO(Ph2P(O)CH2CH2P(Ph)CH2CH2PPh2)(SeC6H2Me3-2,4,6)2]. This is the first example of a structurally characterized molybdenum(IV)oxo-selenolato complex. It contains a chelating triphosphine mono-oxide ligand. The formation can be understood in terms of an oxidative addition of dioxygen to the metal centre followed by oxygen atom transfer to the triphos ligand and reduction of molybdenum to molybdenum(IV).
• Scheer, M; Kolbe, A.; Herrmann, E., Zeitschrift fur Anorganische und Allgemeine Chemie
  作者：Scheer, M、Kolbe, A.、Herrmann, E.、Fedin, V. P.、Fedorov, V. E.、et al.

  DOI：——

  日期：——
• Gilbert, Thomas M.; Landes, Arden M.; Rogers, Robin D., Inorganic Chemistry, 1992, vol. 31, # 16, p. 3438 - 3444
  作者：Gilbert, Thomas M.、Landes, Arden M.、Rogers, Robin D.

  DOI：——

  日期：——