| 1238243-59-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• CAS: 1238243-59-8
• 化学式: C₂₉H₂₄O₂
• 分子量: 404.508
• InChiKey: BIAQGTWDYZZWDY-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  在 magnesium 作用下， 以 四氢呋喃 为溶剂， 以30%的产率得到
  参考文献：
  名称：

  Synthesis and structural characterization of two donor-functionalized terphenyl magnesium compounds

  摘要：

  The synthesis and structural characterization of two novel donor-functionalized terphenyl magnesium compounds, namely (Danip)(2)Mg (1) [Danip = 2,6-di(o-anisyl)phenyl] and [DinapOMg(THF)](2) (Dinap = 2,6-di(o-2-methoxynaphthyl)phenyl; DinapO = 2-(o-2-methoxynaphthyl)-6-(o-2-naphthoxide)phenyl) is reported. Compound 1 represents a first structurally authenticated bis terphenyl magnesium compound, while the molecular structure of dimeric tetrahydrofuran solvated 2 shows a five-coordinate magnesium atom stabilized by a partially demethylated dianionic mixed arylether/aryloxide terphenyl ligand (= DinapO). (C) 2010 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.03.002