(C6H5)4SbONCHC6H3(OH)-2-Br-5 | 422310-78-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: (C6H5)4SbONCHC6H3(OH)-2-Br-5
• CAS: 422310-78-9
• 化学式: C₃₁H₂₅BrNO₂Sb
• 分子量: 645.199
• InChiKey: YAXYCBLLIJYBDT-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  5.03
• 重原子数：
  36.0
• 可旋转键数：
  7.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  41.82
• 氢给体数：
  1.0
• 氢受体数：
  3.0

反应信息

• 作为产物：
  描述：

  pentaphenylantimony 、 2-hydroxy-5-bromobenzaldoxime 以 not given 为溶剂， 以96%的产率得到(C6H5)4SbONCHC6H3(OH)-2-Br-5
  参考文献：
  名称：

  摘要：

  Reactions of pentaphenyl- and penta-p-tolylantimony with benzophenone oxime or triarylantimony bis(benzophenone oximate) yield tetraarylantimony benzophenone oximates. Triarylantimony bis(benzophenone oximates) were prepared by oxidative addition from triarylstibine and benzophenone oxime in the presence of hydrogen peroxide. X-ray diffraction analysis was performed to show that benzophenone oxime is a dimer and tetraphenylantimony benzophenone oximate has a trigonal bipyramidal antimony atom and an axial oxime oxygen atom.

  DOI：

  10.1023/a:1020474021779