molybdocene bis(S-3,5-bis(trifluoromethyl)thiophenol) | 901311-68-0

• 英文名称: molybdocene bis(S-3,5-bis(trifluoromethyl)thiophenol)
• CAS: 901311-68-0
• 化学式: C₂₆H₁₆F₁₂MoS₂
• 分子量: 716.466
• InChiKey: SOZRLSAYWARVLZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二氯二茂钼 、 3,5-双(三氟甲基)苯硫酚 在 NaOH 作用下， 以 水 为溶剂， 生成 molybdocene bis(S-3,5-bis(trifluoromethyl)thiophenol)
  参考文献：
  名称：

  Synthesis and Hydrolysis of Thiol Derivatives of Molybdocene Dichloride Incorporating Electron-Withdrawing Substituents

  摘要：

  Hydrolysis studies of derivatives of molybdocene dichloride in which the two chloride ligands were replaced by 3,5-bis(trifluoromethyl) thiophenol, 3,5-bis(trifluoromethyl) benzyl thiol, and 2,2,2-trifluoroethane thiol ligands confirmed that the electron-withdrawing groups affect the lability of the Mo-S bonds and promote slow generation of the putative biologically active species "Cp2Mo2+"; the trifluoroethane thiol derivative underwent 50% hydrolysis in 14 h in 10% D2O/DMSO-d(6). The structure of molybdocene bis(S-3,5-bis(trifluoromethyl) benzyl thiol) was confirmed by X-ray crystal structure analysis.

  DOI：

  10.1021/om060133e