1-Methyl-4,5-diphenyl-2-thiophen-2-yl-1H-imidazole | 85059-16-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 1-Methyl-4,5-diphenyl-2-thiophen-2-yl-1H-imidazole
• 英文别名: 1-Methyl-4,5-diphenyl-2-thiophen-2-ylimidazole
• CAS: 85059-16-1
• 化学式: C₂₀H₁₆N₂S
• 分子量: 316.426
• InChiKey: RYBCZCHHLCDSAM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  23
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  46.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-Methyl-4,5-diphenyl-2-thiophen-2-yl-1H-imidazole 在 正丁基锂 、 15-冠醚-5 、 potassium tert-butylate 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 生成 1-Methyl-2-{5-[(E)-2-(4-nitro-phenyl)-vinyl]-thiophen-2-yl}-4,5-diphenyl-1H-imidazole
  参考文献：
  名称：

  New class of imidazoles incorporated with thiophenevinyl conjugation pathway for robust nonlinear optical chromophores

  摘要：

  A new series of thermally stable heterocyclic imidazole-based nonlinear optical chromophores has been developed. These chromophores possess a thiophene based stilbene conjugation pathway with a nitro acceptor group attached to the phenyl end. This feature leads to robust chromophores with high thermal stability and enhanced molecular nonlinearity. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(00)02143-2
• 作为产物：
  描述：

  联苯甲酰 在 乙酸铵 、 potassium carbonate 作用下， 以 溶剂黄146 为溶剂， 生成 1-Methyl-4,5-diphenyl-2-thiophen-2-yl-1H-imidazole
  参考文献：
  名称：

  New class of imidazoles incorporated with thiophenevinyl conjugation pathway for robust nonlinear optical chromophores

  摘要：

  A new series of thermally stable heterocyclic imidazole-based nonlinear optical chromophores has been developed. These chromophores possess a thiophene based stilbene conjugation pathway with a nitro acceptor group attached to the phenyl end. This feature leads to robust chromophores with high thermal stability and enhanced molecular nonlinearity. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(00)02143-2

文献信息

• A novel approach to synthesis of tricyanovinylthiophene for heterocyclic imidazole nonlinear optical chromophores
  作者：Xiu R. Bu、Haiying Li、Donald Van Derveer、Eric A. Mintz

  DOI：10.1016/0040-4039(96)01638-3

  日期：1996.10

  A new synthetic method for tricyanovinylation has been developed to prepare a series of novel NLO imidazole chromophores containing a tricyanovinyl acceptor coupled with thiophene spacer.

  已开发出一种新的三氰基乙烯基化合成方法，以制备一系列新型的NLO咪唑发色团，其中含有三氰基乙烯基受体和噻吩间隔基。
• CAHAEBA EH. P.; TANASEJCHUK B. S., MORDOVSK. YH-T., CAPAHCK, 1981. 6 S., BIBLIOGR. 2 NAZV. (PYK DEP V ONIITE+
  作者：CAHAEBA EH. P.、 TANASEJCHUK B. S.

  DOI：——

  日期：——