1-methyl-2,3,4,5-tetraphenyl-1-germacyclopenta-2,4-diene | 202345-73-1

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 1-methyl-2,3,4,5-tetraphenyl-1-germacyclopenta-2,4-diene
• CAS: 202345-73-1
• 化学式: C₂₉H₂₄Ge
• 分子量: 445.1
• InChiKey: KMAQXSRGDWKYPW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.16
• 重原子数：
  30.0
• 可旋转键数：
  4.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  1,4-dilithio-1,2,3,4-tetraphenylbutadiene 在 LiAlH₄ 作用下， 以 乙醚 为溶剂， 生成 1-methyl-2,3,4,5-tetraphenyl-1-germacyclopenta-2,4-diene
  参考文献：
  名称：

  摘要：

  The electrochemical behavior of the sila-, germa-, and stannacyclopentadienes (metalloles) was studied by cyclic voltammetry. The oxidation and reduction mechanisms of these heterocyclic compounds were investigated. A new method for generation of tetraphenylgermole dianion involving the electrochemical reduction of the corresponding dichlorogermole is proposed. Electrochemical oxidation of the metallole dianions was first studied taking tetraphenylgermole dianion as an example.

  DOI：

  10.1023/a:1015084831035