[Cu(N-ethyl-1,2-diaminoethane)(1,1-dicyano-2,2-ethylenedithiolate)] | 189317-52-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: [Cu(N-ethyl-1,2-diaminoethane)(1,1-dicyano-2,2-ethylenedithiolate)]
• CAS: 189317-52-0
• 化学式: C₈H₁₂CuN₄S₂
• 分子量: 291.888
• InChiKey: GRNOHYFCBLQPNV-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N-乙基乙二胺 、 copper(II) choride dihydrate 、 dissodium 1,1-dicyanoethylene-2,2-dithiolate*3H2O 以 甲醇 为溶剂， 以66%的产率得到[Cu(N-ethyl-1,2-diaminoethane)(1,1-dicyano-2,2-ethylenedithiolate)]
  参考文献：
  名称：

  Influence of substituents within bidentate nitrogenous bases on the spectra of mixed-ligand (1,1-dithiolato)copper(II) and nickel(II) chelates

  摘要：

  A series of mixed-ligand copper(II) and Nickel(II) chelates, [M(enR)(i-MNT)], containing the dianion of 1,1-dicyano-2,2-ethlenedithiole, (i-MNT)(2-), and an N-alkyl substituted 1,2-diaminoethane, enR, were prepared and characterised. From the IR spectra of [M(enR)(i-MNT)] it transpires that the influence of the groups attached to the diamine on group vibrations is not as important as that of substituents linked to the >C=C< entity. It is established that the frequency of a strong band in the 1340 to 1550 cm(-1) region is inversely proportional to the interatomic distance of the >C=C< entity. The magnetic behaviour and the electronic excitation and ESR spectra indicated a square-planar structure. The existence of metal(II) in a square-planar environment was confirmed by the X-ray diffraction of [Ni(Et(2)en)(i-MNT)] determined from a single microcrystal (monoclinic, space group P2(1)/n, a=7.277(2), b=8.793(3), c=21.557(3) angstrom, beta=95.07(1)(0), Z=4, R=0.0491, R-w=0.0551)

  DOI：

  10.1016/s0020-1693(96)05413-8