[Ru(bpy)2(tyr-d2)(D2O)](2+) | 878552-77-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: [Ru(bpy)2(tyr-d2)(D2O)](2+)
• 英文别名: [Ru(2,2'-bipyridine)2(tyramine-d2)(D2O)](2+)
• CAS: 878552-77-3
• 化学式: C₂₈H₂₉N₅O₂Ru
• 分子量: 572.609
• InChiKey: BIHSCDPWVYHWEA-JBISRTOLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [Ru(bpy)2(tyr)2]Cl2 、 重水 以 重水 为溶剂， 生成 [Ru(bpy)2(tyr-d2)(D2O)](2+)
  参考文献：
  名称：

  Ruthenium(II) Bipyridyl Complexes as Photolabile Caging Groups for Amines

  摘要：

  The synthesis and characterization of a series of ruthenium bis(bipyridine) complexes where the inorganic moiety acts as a photolabile protecting group is described. Complexes of the type [Ru(bpy)(2)L-2](+) where bpy = 2,2'-bipyridine and L = butylamine, gamma-aminobutyric acid, tyramine, tryptamine, and serotonin were studied by nuclear magnetic resonance, cyclic voltammetry, and electronic absorption spectroscopy. In all cases, ligands are coordinated by the amine group. The complexes are stable in water for several days and deliver one molecule of ligand upon irradiation with visible light (450 nm). These properties make them suitable for their use as biological caged compounds.

  DOI：

  10.1021/ic0512983