4-{1-[(2-pyridine-2-yl)hydrazono]ethyl}benzene-1,3-diol | 1125749-44-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 4-{1-[(2-pyridine-2-yl)hydrazono]ethyl}benzene-1,3-diol
• 英文别名: 4-[C-methyl-N-(pyridin-2-ylamino)carbonimidoyl]benzene-1,3-diol
• CAS: 1125749-44-1
• 化学式: C₁₃H₁₃N₃O₂
• 分子量: 243.265
• InChiKey: RRGRHODFOMKBMB-UHFFFAOYSA-N

物化性质

• 沸点：
  458.3±37.0 °C(predicted)
• 密度：
  1.26±0.1 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  77.7
• 氢给体数：
  3
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  2-肼吡啶 、 2,4-二羟基苯乙酮 在 硫酸 作用下， 以 甲醇 为溶剂， 反应 8.0h， 以50%的产率得到4-{1-[(2-pyridine-2-yl)hydrazono]ethyl}benzene-1,3-diol
  参考文献：
  名称：

  HYDRAZONE COMPOUND, HYDRAZONE COMPOUND FOR FORMING COMPLEX, LIGAND FOR FORMING METAL COMPLEX, AND MONOMER FOR MANUFACTURING POLYMER COMPOUND

  摘要：

  下列是一种由通式（1）表示的腙类化合物，一种用于形成金属配合物的腙类化合物，该化合物由通式（1）表示，并通过配位至至少一种金属物种形成金属配合物，一种包括腙类化合物的形成金属配合物的配体，以及一种包括腙类化合物的制造聚合物化合物的单体：其中，Py代表2-吡啶基，3-吡啶基或4-吡啶基。

  公开号：

  US20090062507A1

文献信息

• CATALYST USING HYDRAZONE COMPOUND, HYDRAZONE POLYMER COMPOUND, AND CATALYST USING HYDRAZONE POLYMER COMPOUND
  申请人：Masuda Hideki

  公开号：US20090062506A1

  公开（公告）日：2009-03-05

  A catalyst obtained by calcining a hydrazone metal complex in which at least one catalytic metal species is coordinated to a hydrazone compound represented by a General Formula (1) below, a hydrazone polymer compound including at least a structural unit derived from a hydrazone compound represented by the General Formula (1) below as a repeating unit, and a catalyst obtained by calcining a hydrazone polymer metal complex in which at least one catalytic metal species is coordinated to a hydrazone polymer compound including at least a structural unit derived from a hydrazone compound represented by the General Formula (1) below: wherein, Py represents a 2-pyridyl group, a 3-pyridyl group, or a 4-pyridyl group.

  通过在至少一个催化金属种类配位到以下一般式（1）所表示的腙化合物的腙金属配合物中焙烧得到的催化剂，其中Py代表2-吡啶基、3-吡啶基或4-吡啶基；包括至少一个源自以下一般式（1）所表示的腙化合物的结构单元作为重复单元的腙化聚合物化合物，以及通过在至少一个催化金属种类配位到包括至少一个源自以下一般式（1）所表示的腙化合物的结构单元作为重复单元的腙化聚合物化合物中焙烧得到的催化剂。
• Hydrazone compound, hydrazone compound for forming complex, ligand for forming metal complex, and monomer for manufacturing polymer compound
  申请人：Toyota Jidosha Kabushiki Kaisha

  公开号：US07951903B2

  公开（公告）日：2011-05-31

  A hydrazone compound represented by a General Formula (1) below, a hydrazone compound for forming a metal complex, which is represented by the General Formula (1) below and forms a metal complex by coordination to at least one metal species, a ligand for forming a metal complex including the hydrazone compound, and a monomer for manufacturing a polymer compound including the hydrazone compound: wherein, Py represents a 2-pyridyl group, a 3-pyridyl group, or a 4-pyridyl group.

  以下是一种由一般式（1）表示的酰肼化合物，一种用于形成金属配合物的酰肼化合物，由一般式（1）表示，并通过与至少一种金属物种的配位形成金属配合物，包括酰肼化合物的形成金属配合物的配体，以及包括酰肼化合物的制造聚合物化合物的单体： 其中，Py代表2-吡啶基，3-吡啶基或4-吡啶基。
• Catalyst using hydrazone compound, hydrazone polymer compound, and catalyst using hydrazone polymer compound
  申请人：Toyota Jidosha Kabushiki Kaisha

  公开号：US07960501B2

  公开（公告）日：2011-06-14

  A catalyst obtained by calcining a hydrazone metal complex in which at least one catalytic metal species is coordinated to a hydrazone compound represented by a General Formula (1) below, a hydrazone polymer compound including at least a structural unit derived from a hydrazone compound represented by the General Formula (1) below as a repeating unit, and a catalyst obtained by calcining a hydrazone polymer metal complex in which at least one catalytic metal species is coordinated to a hydrazone polymer compound including at least a structural unit derived from a hydrazone compound represented by the General Formula (1) below: wherein, Py represents a 2-pyridyl group, a 3-pyridyl group, or a 4-pyridyl group.

  通过在至少一个催化金属种类配位到下述一般式（1）所代表的腙化合物的腙金属配合物中煅烧而得到的催化剂，其中，一般式（1）如下：其中，Py代表2-吡啶基、3-吡啶基或4-吡啶基的基团；以及包括至少一个以一般式（1）所代表的腙化合物作为重复单元的腙化聚合物化合物的腙聚合物金属配合物，其中至少一个催化金属种类配位到包括至少一个以一般式（1）所代表的腙化合物作为结构单元的腙聚合物化合物。