Perfluorazooctan | 3829-39-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Perfluorazooctan
• 英文别名: (E)-bis(1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctyl)diazene
• CAS: 3829-39-8
• 化学式: C₁₆F₃₄N₂
• 分子量: 866.135
• InChiKey: HZBIPQWVEKXYMJ-WYYOLBRMSA-N

物化性质

• 沸点：
  67-75 °C
• 密度：
  1.79±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  12
• 重原子数：
  52
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  24.7
• 氢给体数：
  0
• 氢受体数：
  36

反应信息

• 作为反应物：
  描述：

  Perfluorazooctan 以 various solvent(s) 为溶剂， 生成 全氟十六烷
  参考文献：
  名称：

  Perfluorooctylation of aromatic compounds with perfluoroazooctane upon 185 nm irradiation in a two-phase system

  摘要：

  利用全氟辛烷 (E)-1 在 185 纳米波长照射下的光解作用，开发出了一种制备全氟辛基芳香族和杂芳香族化合物的有效方法。事实证明，使用由(E)-1 的全氟己烷溶液和适当的芳香族化合物组成的两相体系可以有效地进行该反应。根据量子产率、光强依赖性和紫外-可见光谱，还研究了 (E)-1 在 185 纳米辐照下的光解机理。研究表明，(E)-1 通过一次光子吸收发生光异构化，生成 (Z)- 异构体，随后通过第二次光子吸收挤出氮。

  DOI：

  10.1039/a707171j

文献信息

• Photolysis of Perfluoroazooctane in Perfluorohexane upon 185 nm Irradiation
  作者：Takako Nakamura、Akira Yabe

  DOI：10.1246/cl.1995.533

  日期：1995.7

  The photolysis of perfluoroazooctane in perfluorohexane upon 185 nm irradiation was investigated by means of quantum yield, light intensity dependence, and UV-vis spectra of the photolysis of perfluoroazooctane. Perfluoroazooctane (trans isomer) was photoisomerized by one photon absorption to cis isomer, followed by extrusion of nitrogen by another photon absorption.

  通过量子产率、光强度依赖性和全氟偶氮辛烷光解的紫外-可见光谱研究了全氟偶氮辛烷在 185 nm 照射下在全氟己烷中的光解。全氟偶氮辛烷（反式异构体）通过一个光子吸收光异构化为顺式异构体，然后通过另一个光子吸收挤出氮。
• SURFACE-MODIFIED NANOFILLER AND POLYMER COMPOSITE MATERIAL
  申请人：DAIKIN INDUSTRIES, LTD.

  公开号：EP1908801A1

  公开（公告）日：2008-04-09

  The object of the present invention is to offer a polymer composite material that provides superior heat resistance, mechanical physical properties, substance permeation barrier properties, flame retardant properties, electrical conductivity and the like. Moreover, another object of the present invention is to offer a novel surface-modified nanofiller that utilizes this type of polymer composite material. The polymer composite material contains nanofillers, fluorocompounds and polymers. The fluorocompounds bond to the surface of the nanofillers. The nanofillers to which fluorocompounds are surface-bonded are mixed with or dispersed in polymers.

  本发明的目的是提供一种聚合物复合材料，它具有优异的耐热性、机械物理性能、物质渗透阻隔性能、阻燃性能、导电性能等。此外，本发明的另一个目的是提供一种利用这种聚合物复合材料的新型表面改性纳米填料。聚合物复合材料包含纳米填料、含氟化合物和聚合物。氟化合物与纳米填料表面结合。与氟化合物表面结合的纳米填料与聚合物混合或分散在聚合物中。
• GAS PHASE APPROACH TO IN-SITU/EX-SITU FUNCTIONALIZATION OF POROUS GRAPHITIC CARBON VIA RADICAL-GENERATED MOLECULES
  申请人：Linford Matthew R.

  公开号：US20110210056A1

  公开（公告）日：2011-09-01

  Embodiments disclosed herein include graphitic stationary phase materials functionalized through a gas-phase functionalization reaction, as well as and methods for making and using these materials, including the use of these materials in separation technologies such as, but not limited to, chromatography and solid phase extraction. In an embodiment, a functionalized graphitic stationary phase material may be prepared from high surface area porous graphitic carbon and a radical forming volatilized functionalizing agent. The radical forming volatilized functionalizing agent produces an intermediate that forms a covalent bond with the surface of the porous graphitic material and imparts desired properties to the surface of the graphitic carbon.
• US7989535B2
  申请人：——

  公开号：US7989535B2

  公开（公告）日：2011-08-02
• Perfluorooctylation of aromatic compounds with perfluoroazooctane upon 185 nm irradiation in a two-phase system
  作者：Takako Nakamura、Yoshinori Koga

  DOI：10.1039/a707171j

  日期：——

  An efficient method for the preparation of perfluorooctylated aromatic and heteroaromatic compounds has been developed using photolysis of perfluoroazooctane (E)-1 upon 185 nm irradiation. The use of a two-phase system made up of a perfluorohexane solution of (E)-1 and a suitable aromatic compound has proved efficient for this reaction. The photolytic mechanism of (E)-1 upon 185 nm irradiation has also been investigated on the basis of quantum yield, light intensity dependence and UV–VIS spectra. It is shown that (E)-1 is photoisomerized by one photon absorption to the (Z)-isomer, with subsequent extrusion of nitrogen by a second photon absorption.

  利用全氟辛烷 (E)-1 在 185 纳米波长照射下的光解作用，开发出了一种制备全氟辛基芳香族和杂芳香族化合物的有效方法。事实证明，使用由(E)-1 的全氟己烷溶液和适当的芳香族化合物组成的两相体系可以有效地进行该反应。根据量子产率、光强依赖性和紫外-可见光谱，还研究了 (E)-1 在 185 纳米辐照下的光解机理。研究表明，(E)-1 通过一次光子吸收发生光异构化，生成 (Z)- 异构体，随后通过第二次光子吸收挤出氮。