[Pd2Cl2(η-allyl)2(bis(2,6-diphenylphosphino)picolinamide)] | 808133-18-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• 英文名称: [Pd2Cl2(η-allyl)2(bis(2,6-diphenylphosphino)picolinamide)]
• 英文别名: 2-N,6-N-bis(diphenylphosphanyl)pyridine-2,6-dicarboxamide;chloropalladium(1+);prop-1-ene
• CAS: 808133-18-8
• 化学式: C₃₇H₃₅Cl₂N₃O₂P₂Pd₂
• 分子量: 899.397
• InChiKey: FBTQKWFASGCVKN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  8.02
• 重原子数：
  48
• 可旋转键数：
  8
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  71.1
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  bis(η3-allyl-μ-chloropalladium(II)) 、 bis(2,6-diphenylphosphino)picolinamide 以 二氯甲烷 为溶剂， 以91%的产率得到[Pd2Cl2(η-allyl)2(bis(2,6-diphenylphosphino)picolinamide)]
  参考文献：
  名称：

  Synthesis and coordination of 2-diphenylphosphinothiophenocarboxamide and bis(2,5-diphenylphosphinepicolinamide)

  摘要：

  2-Diphenylphosphinothiophenocarboxamide (dpptc) and bis(2,5-diphenylphosphinepicolinamide) (bdpppa) have been prepared and complexed with a variety of metals. Bdpptc behaves as a monodentate P donor ligand and can become bidentate by making use of the C=O site. Bdpppa behaves as a P donor bridging ligand. In many cases, the X-ray structures reveal that the ligand backbone geometry is strongly influenced by intramolecular H-bonding. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.09.014