| 883716-25-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• CAS: 883716-25-4
• 化学式: C₁₁₄H₁₂₆N₈Ni₂O₈
• 分子量: 1853.68
• InChiKey: QPCKAUGVLABDGA-JKSIOJQSSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 溴丙烷 在 NaH 作用下， 以 四氢呋喃 为溶剂， 以55%的产率得到
  参考文献：
  名称：

  Electrochemically Triggered Open and Closed Pacman Bis-metalloporphyrins

  摘要：

  A new type of very compact Pacman bis-porphyrin scaffold has been obtained in which a calix[4]arene spacer provides both cofacial preorganization and flexibility. Changes in the distance between the two tetrapyrrolic macrocycles can be triggered by electrochemistry, where closed and open conformers can be interconverted in a handclapping motion.

  DOI：

  10.1021/ja058132l
• 作为产物：
  描述：

  5-ethynyl-2,3,7,8,12,13,17,18-octaethylporphyrinatonickel(II) 、 28,39-Diiodo-3,6,9,12,15,18-hexaoxahexacyclo[18.15.7.126,30.137,41.02,32.019,24]tetratetraconta-1(35),2(32),19(24),20,22,26(44),27,29,33,37,39,41(43)-dodecaene-43,44-diol 在 Pd(PPh₃)2Cl₂ 、 CuI 、 (C₂H₅)3N 作用下， 以 甲苯 为溶剂， 以25%的产率得到
  参考文献：
  名称：

  Electrochemically Triggered Open and Closed Pacman Bis-metalloporphyrins

  摘要：

  A new type of very compact Pacman bis-porphyrin scaffold has been obtained in which a calix[4]arene spacer provides both cofacial preorganization and flexibility. Changes in the distance between the two tetrapyrrolic macrocycles can be triggered by electrochemistry, where closed and open conformers can be interconverted in a handclapping motion.

  DOI：

  10.1021/ja058132l