| 153347-41-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• CAS: 153347-41-2
• 化学式: C₂H₆O*C₁₉H₂₆Cl₂N₂O₂Pd
• 分子量: 537.823
• InChiKey: SPBMIPDZTNZHJO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  potassium tetrachloropalladate(II) 、 1,3-bis(2-hydroxybenzylamino)-2,2-dimethylpropane 在 ethanol 作用下， 以 乙醇 、 水 为溶剂， 以<20的产率得到
  参考文献：
  名称：

  Palladium(II) complexes of N2O2 and N2S2 ligands: Syntheses and X-ray crystal structures

  摘要：

  Palladium(II) complexes of an imine-thiophene ligand N,N' bis(1-methylenethiophene)-1,3-diaminopropane and an amine-phenol ligand N,N'-bis(2-hydroxybenzyl)l,3-diamino-2,2-dimethyl-propane were synthesized by reacting K2PdCl4 with alcoholic solutions of the ligands. X-ray struc ures of the complexes were determined using data from a CAD-4 Nonius diffractometer (Mo K alpha radiation). The structures were solved by conventional methods resulting in R factors of 0.044 and 0.061 using 1841 and 2241 independent reflections, respectively. Crystal data: Complex I, orthorhombic, space group Pbca, a=11.323(2), b=14.819(2), c=23.873(3)A, V=4006(1)Angstrom(3), Z=g. Complex III Space group P2(I)/c, a=9.169(2), b=31.920(4), c=8.902(6), beta=90.38(2)degrees, V=2605(1)Angstrom(3). Z=4. Both complexes showed coordination of the ligands through the nitrogens only while the sulphur and the oxygen atoms were uncoordinated. Square planar coordination is completed by cis chloro ligands.

  DOI：

  10.1007/bf01185542