2-methyl-4-(naphthalen-2-yl)thiophene | 1580444-07-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2-methyl-4-(naphthalen-2-yl)thiophene
• 英文别名: 2-Methyl-4-naphthalen-2-ylthiophene
• CAS: 1580444-07-0
• 化学式: C₁₅H₁₂S
• 分子量: 224.326
• InChiKey: KFORQHZMXPXLKC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  16
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3-溴丙炔 、 2-溴代-2-乙酰基萘 在 indium 、 硫酸 、 硫代乙酰胺 作用下， 以 四氢呋喃 、 水 、 二氯甲烷 、 乙醇 为溶剂， 反应 3.0h， 以22%的产率得到2-methyl-4-(naphthalen-2-yl)thiophene
  参考文献：
  名称：

  γ-卤代烯酮：由卤代丙烯酰基合成的方法及其在制备五元环杂环化合物中的应用

  摘要：

  已开发出一种简单的方法来合成γ-卤代烯酮。该方法采用的序列涉及初始的铟介导的苯甲酰卤与炔丙基溴的烯丙基化反应。该过程之后是形成的高烯丙基卤代醇的酸促进的重排反应。可以将新方法结合到有效合成各种五元杂环化合物的途径中。

  DOI：

  10.1021/jo5001274

文献信息

• POLYMERIZABLE COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER, AND OPTICAL ANISOTROPIC BODY
  申请人：ZEON CORPORATION

  公开号：US20150274872A1

  公开（公告）日：2015-10-01

  The present invention pertains to: a polymerizable compound represented by a formula (I); a polymerizable composition comprising the polymerizable compound and an initiator; a polymer obtained by polymerizing the polymerizable compound or the polymerizable composition; and an optically anisotropic article comprising the polymer. The present invention provides a polymerizable compound, a polymerizable composition, and a polymer that have a practical low melting point, exhibit excellent solubility in a general-purpose solvent, can be produced at low cost, and can produce an optical film that achieves uniform conversion of polarized light over a wide wavelength band, and also provide an optically anisotropic article. [In the formula: Y 1 to Y 8 are a chemical single bond, —O—, —O—C(═O)—, —O—C(═O)—O—, etc.; G 1 and G 2 are a divalent aliphatic group having 1 to 20 carbon atoms, etc.; Z 1 and Z 2 are an alkenyl group having 2 to 10 carbon atoms that is substituted with a halogen atom, or unsubstituted, etc.; A x is a group represented by a formula (II), wherein X is a nitrogen atom, etc.; R a and R b are a hydrogen atom, an aromatic hydrocarbon ring group having 1 to 20 carbon atoms, etc.; A y is a hydrogen atom, the group represented by the formula (II), etc.; A 1 is a trivalent aromatic group, etc; A 2 and A 3 are a divalent alicyclic hydrocarbon group having 3 to 30 carbon atoms, etc.; A 4 and A 5 are a divalent aromatic group having 4 to 30 carbon atoms, etc.; Q 1 is a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, etc.]
• US9777096B2
  申请人：——

  公开号：US9777096B2

  公开（公告）日：2017-10-03