2,2'-(1,3-propylenedioxy)-6,6'-dinitro-1,1'-binaphthalene | 184106-99-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2,2'-(1,3-propylenedioxy)-6,6'-dinitro-1,1'-binaphthalene
• 英文别名: 2,2'-(1,4-propylenedioxy)-6,6'-dinitro-1,1'-binaphthalene；6,22-Dinitro-12,16-dioxapentacyclo[15.8.0.02,11.03,8.020,25]pentacosa-1(17),2(11),3(8),4,6,9,18,20(25),21,23-decaene；6,22-dinitro-12,16-dioxapentacyclo[15.8.0.02,11.03,8.020,25]pentacosa-1(17),2(11),3(8),4,6,9,18,20(25),21,23-decaene
• CAS: 184106-99-8；193477-92-8；193477-93-9
• 化学式: C₂₃H₁₆N₂O₆
• 分子量: 416.39
• InChiKey: BRHTVAYZWCNIHS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  31
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  110
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  12,16-Dioxapentacyclo[15.8.0.02,11.03,8.020,25]pentacosa-1(17),2(11),3,5,7,9,18,20,22,24-decaene 在 硝酸 、 溶剂黄146 作用下， 反应 16.0h， 以4%的产率得到2,2'-(1,3-propylenedioxy)-6,6'-dinitro-1,1'-binaphthalene
  参考文献：
  名称：

  Synthesis and characterization of optically active cyclic 6,6′-dinitro-1,1′-binaphthyl-2,2′-diethers

  摘要：

  A series of racemic and enantiomerically pure 6,6'-dinitro-1,1'-binaphthyl-2,2'-diethers 1 have been synthesized by the nitration of the corresponding cyclic ethers and both the reactivity of nitration and the (chir)optical properties proved to be very sensitive for the chain length of the ether bridge. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0957-4166(97)00185-7

文献信息

• Synthesis and characterization of optically active cyclic 6,6′-dinitro-1,1′-binaphthyl-2,2′-diethers
  作者：J.J.G.S. van Es、H.A.M. Biemans、E.W. Meijer

  DOI：10.1016/s0957-4166(97)00185-7

  日期：1997.6

  A series of racemic and enantiomerically pure 6,6'-dinitro-1,1'-binaphthyl-2,2'-diethers 1 have been synthesized by the nitration of the corresponding cyclic ethers and both the reactivity of nitration and the (chir)optical properties proved to be very sensitive for the chain length of the ether bridge. (C) 1997 Elsevier Science Ltd.