6,7-diacetoxy-1,2,3,4-tetrahydro-naphthalene | 103272-38-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 四氢化萘
• 英文名称: 6,7-diacetoxy-1,2,3,4-tetrahydro-naphthalene
• 英文别名: 6,7-Diacetoxy-1,2,3,4-tetrahydro-naphthalin；(3-Acetyloxy-5,6,7,8-tetrahydronaphthalen-2-yl) acetate；(3-acetyloxy-5,6,7,8-tetrahydronaphthalen-2-yl) acetate
• CAS: 103272-38-4
• 化学式: C₁₄H₁₆O₄
• 分子量: 248.279
• InChiKey: UEFAQVSMJDVADR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  6,7-diacetoxy-1,2,3,4-tetrahydro-naphthalene 在 三氯化铝 作用下， 生成 1-(2,3-dihydroxy-5,6,7,8-tetrahydro-[1]naphthyl)-ethanone
  参考文献：
  名称：

  Momose; Goya, Chemical and pharmaceutical bulletin, 1959, vol. 7, p. 849

  摘要：

  DOI：
• 作为产物：
  描述：

  2,3-dihydroxy-5,6,7,8-tetrahydronaphthalene 、 乙酸酐 在 硫酸 作用下， 生成 6,7-diacetoxy-1,2,3,4-tetrahydro-naphthalene
  参考文献：
  名称：

  Momose et al., Pharmaceutical Bulletin, 1955, vol. 3, p. 401,402

  摘要：

  DOI：

文献信息

• Efficient <i>ortho</i>-Oxidation of Phenols with Diacyl Peroxides
  作者：Masahiro Tada、Risa Ishiguro、Ryohei Izumi

  DOI：10.1248/cpb.56.239

  日期：——

  A stable symmetric diacyl peroxide, m-chlorobenzoyl peroxide (mCBPO), and an asymmetric diacyl peroxide, chloroacetyl m-chlorobenzoyl peroxide (CAMCBPO), were synthesized from m-chloroperbenzoic acid. Both peroxides oxidized phenols selectively at the ortho position predoninantly. CAMCBPO gave para-oxidized compounds as minor products from some phenols. The improvement of the yield of ortho-oxidation of phenols with mCBPO was also reported.

  从间氯过苯甲酸出发，合成了稳定的对称二酰基过氧化物间氯苯甲酰过氧化物（mCBPO）和非对称二酰基过氧化物氯乙酰基间氯苯甲酰过氧化物（CAMCBPO）。这两种过氧化物主要选择性地在苯酚的邻位进行氧化。从某些苯酚出发，CAMCBPO得到了少量对位氧化产物。还报道了使用mCBPO提高苯酚邻位氧化产率的方法。
• CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
  申请人：Basell Poliolefine Italia S.r.l.

  公开号：US20150141594A1

  公开（公告）日：2015-05-21

  A catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) in which the R groups equal to or different from each other, are C 1 -C 15 hydrocarbon groups, the R 1 -R 2 groups, equal to or different from each other, are hydrogen, halogen or C 1 -C 15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, which can be fused together to form one or more cycles; n and m are integer from 0 to 3 with the proviso that at least one of them is different from 0 and that diisobutyl o-phenylenediacetate is excluded.
• Momose et al., Pharmaceutical Bulletin, 1955, vol. 3, p. 401,402
  作者：Momose et al.

  DOI：——

  日期：——
• Momose; Goya, Chemical and pharmaceutical bulletin, 1959, vol. 7, p. 849
  作者：Momose、Goya

  DOI：——

  日期：——