2,3,9,10,16,17,23,24-octakis(butoxy)-1,4,8,11,15,18,22,25-(octaaza)phthalocyanine zinc(II) | 730965-06-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 咪唑并嘧啶类
• 英文名称: 2,3,9,10,16,17,23,24-octakis(butoxy)-1,4,8,11,15,18,22,25-(octaaza)phthalocyanine zinc(II)
• 英文别名: (2,3,9,10,16,17,23,24-octabutoxy-1,4,8,11,15,18,22,25-octaazaphthalocyaninato)zinc(II)
• CAS: 730965-06-7
• 化学式: C₅₆H₇₂N₁₆O₈Zn
• 分子量: 1162.68
• InChiKey: NUFOMFXIDPDYBV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  5,6-dibutoxypyrazine-2,3-dicarbonitrile 在 zinc chloride * 2 quinoline 作用下， 反应 1.0h， 以14%的产率得到2,3,9,10,16,17,23,24-octakis(butoxy)-1,4,8,11,15,18,22,25-(octaaza)phthalocyanine zinc(II)
  参考文献：
  名称：

  The synthesis, photochemical and photophysical properties of zinc aryloxy- and alkyloxy azaphthalocyanines

  摘要：

  Octasubstituted zinc tetrapyrazinoporphyrazines bearing butyloxy, octyloxy, 2,6-diisopropylphenoxy and 4-(hydroxymethyl)phenoxy substituents were synthesized from the corresponding 5,6-disubstituted pyrazine-2,3-dicarbonitriles using Zn(quinoline)(2)Cl-2 in yields varying from 14 to 44%. The reaction procedure proved to be efficient for the synthesis of both alkyloxy- and aryloxy- substituted zinc tetrapyrazinoporphyrazines and did not require strictly anhydrous conditions. Optimal cyclotetramerization conditions were identified for each derivative, in terms of reaction temperature, as overheating cleaved the ether bond leaving a vacant OH group on the macrocycle. The photochemical and photophysical properties of the synthesized compounds were investigated in pyridine. Singlet oxygen quantum yields (Phi(Delta)) ranged from 0.49 to 0.61 and high fluorescence quantum yields (Phi(F)) of similar to 0.30 were observed for non-aggregated compounds. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2010.03.023