| 27216-81-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• CAS: 27216-81-5
• 化学式: CH₅N*Cl₃Ge*H
• 分子量: 211.014
• InChiKey: JUINJPYLBHNHCB-UHFFFAOYSA-O

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  盐酸甲胺 、 germanium(II) chloride 以 盐酸 为溶剂， 生成
  参考文献：
  名称：

  Structural and spectroscopic studies on trimorphous MeNH3GeCl3

  摘要：

  X-ray diffraction, DTA and Raman scattering experiments on powder and single crystals have been carried out to study the structure and phase transitions of MeNH(3)GeCl(3). The compound crystallizes in an orthorhombically distorted perowskite structure and undergoes two phase transitions at 348K and 403K into a rhomboedric HT1 and finally a cubic HT2 modification. On cooling down to 10K, no further symmetry reduction was detectable. The Raman spectra show that the HT-phases are disordered. Assignments for the vibration bands and calculated force constants are given. The HT1-phase is isostructural to RT-CsGeCl3 which shows discontinuities of the dielectric constant at the transition to the cubic structure. In order to quantify the lone pair activity of Ge(II), bond valences were calculated for several compounds AGeCl(3). (A-monovalent cation; e.g. Cs, MeNH(3)).

  DOI：

  10.1016/0022-2860(95)08597-o

文献信息

• Yamada, K.; Isobe, K.; Okuda, T., Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences
  作者：Yamada, K.、Isobe, K.、Okuda, T.、Furukawa, Y.

  DOI：——

  日期：——