| 147361-89-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 咪唑并嘧啶类
• CAS: 147361-89-5
• 化学式: C₄₁H₃₉F₆N₉O₄Rh₂
• 分子量: 1041.62
• InChiKey: CIEOHIPZDIGGOU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  Rh2(N,N'-di-p-tolylformamidinate)2(trifluoroacetate)2(H2O)2 、 6-二甲基氨基嘌呤 以 水 为溶剂， 以55%的产率得到
  参考文献：
  名称：

  Interactions of the Rh24+ formamidinate complex Rh2(μ-form)2(μ-O2CCF3)2(H2O)2 (form=N, N′-di-p-tolylformamidinate anion)with nucleobases and nucleosides

  摘要：

  The Rh2(4+) formamidinate complex Rh2(mu-form)2(mu-O2CCF3)2(H2O)2 (form =N, N'-di-p-tolylformamidinate anion) reaCts with adenine and N,N-dimethyladenine in molar ratio 1:1 and 1:2 giving mono- and bis-axial adducts Rh2(mu-form)2(mu-O2CCF3)2(L)n (L = adenine, N,N-dimethyladenine; n = 1, 2) with the adenine ligands coordinated through the N(3) atoms. In contrast when both the N(3) and N(9) atoms are blocked, the complex reacts in a different way. Adenosine (ado) in fact coordinates through the dimetal core leading to the Rh2(5+) complex Rh2(mu-form)2(O2CCF3)(mu-ado)2 which has been characterized by EPR spectroscopy. In this complex adenosine behaves as a bidentate mono-anionic ligand coordinated at the equatorial positions through N(1) and the deprotonated amino nitrogen. Similarly the complex Rh2(mu-form)2(mu-O2CCF3)2(H2O)2 reacts with cytosine, 1-methylcytosine and cytidine via a mono-electron oxidation leading to the paramagnetic complexes Rh2(mu-form)2(O2CCF3)(mu-L)2 (L = cytosine, 1-methylcytosine, cytidine) with the cytidinic ligands equatorially coordinated through N(3) and the deprotonated amino nitrogen atoms.

  DOI：

  10.1016/s0020-1693(00)82912-6