6-acryloyloxy-2-naphthoic acid | 366448-51-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 6-acryloyloxy-2-naphthoic acid
• 英文别名: 6-acroyloxy-2-naphthoic acid；6-prop-2-enoyloxynaphthalene-2-carboxylic acid
• CAS: 366448-51-3
• 化学式: C₁₄H₁₀O₄
• 分子量: 242.231
• InChiKey: QRMYFOOFOAGDGE-UHFFFAOYSA-N

物化性质

• 沸点：
  440.4±14.0 °C(Predicted)
• 密度：
  1.307±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  4-苯基甲氧基-2-丙基苯酚 、 6-acryloyloxy-2-naphthoic acid 在 甲基磺酰氯 、 三乙胺 、 4-二甲氨基吡啶 作用下， 以 四氢呋喃 为溶剂， 反应 2.0h， 以61.9%的产率得到(4-Phenylmethoxy-2-propylphenyl) 6-prop-2-enoyloxynaphthalene-2-carboxylate
  参考文献：
  名称：

  EP1972612

  摘要：

  公开号：
• 作为产物：
  描述：

  2-羟基-6-萘甲酸 、 丙烯酰氯 在 sodium hydroxide 、 盐酸 作用下， 以 水 为溶剂， 反应 3.0h， 以53.6%的产率得到6-acryloyloxy-2-naphthoic acid
  参考文献：
  名称：

  POLYMERIZABLE COMPOUND AND COMPOSITION CONTAINING THE POLYMERIZABLE COMPOUND

  摘要：

  公开号：

  EP1813594B1

文献信息

• ALKALOID MONOMERS, LIQUID CRYSTAL COMPOSITIONS AND POLYMER NETWORKS DERIVED THEREFROM
  申请人：Goldfinger Marc B.

  公开号：US20110193019A1

  公开（公告）日：2011-08-11

  Disclosed is the chemical synthesis of chiral alkaloid monomers, liquid crystal compositions comprising the chiral alkaloid monomers, and polymerization of the liquid crystal compositions to provide polymer networks with useful cholesteric optical properties and stability.

  公开了手性生物碱单体的化学合成、包含手性生物碱单体的液晶组合物，以及液晶组合物的聚合，以提供具有有用的胆甾光学性能和稳定性的聚合物网络。
• NOVEL POLYMERIZABLE COMPOUNDS
  申请人：Irisawa Masatomi

  公开号：US20090247782A1

  公开（公告）日：2009-10-01

  A novel polymerizable compound of the present invention is represented by the following general formula (I). Due to the presence of a reactive phenolic hydroxyl group at the end of the molecule, it can be reacted easily with various functional compounds and is useful as a monomer and an intermediate for various functional materials, especially as an intermediate for a polymerizable liquid crystal material. wherein R 1 is a hydrogen atom, a methyl group or a halogen atom; R 2 is an optionally substituted alkyl group having 1 to 6 carbon atoms, an optionally substituted alkoxy group having 1 to 6 carbon atoms, a halogen atom or a cyano group; an alkylene group of each of the alkyl and the alkoxy group may be interrupted by an unsaturated bond, an ether bond, a thioether bond or an ester bond; n is an integer from 0 to 14; and m is 0 or 1.

  本发明的一种新型可聚合化合物由以下通式（I）表示。由于分子末端存在反应性酚羟基，因此可以与各种功能化合物容易地反应，作为各种功能材料的单体和中间体特别是作为可聚合液晶材料的中间体。 其中，R1是氢原子，甲基或卤素原子；R2是具有1至6个碳原子的可选取代烷基，具有1至6个碳原子的可选取代烷氧基，卤素原子或氰基；烷基和烷氧基的每个亚烷基可以通过不饱和键，醚键，硫醚键或酯键中断；n是从0到14的整数；m为0或1。
• Polymerizable Compound And Composition Containing The Polymerizable Compound
  申请人：Irisawa Masatomi

  公开号：US20070282087A1

  公开（公告）日：2007-12-06

  The polymerizable compound of the present invention is represented by general formula (1) below and can provide a composition that is polymerizable near ambient temperature and exists in a liquid crystal phase at low temperatures. The composition and a (co)polymer of the polymerizable compound of the present invention are liquid crystal substances useful as optically anisotropic materials. (In the formula, each of rings A 1 to A 3 represents a benzene ring, cyclohexane ring, etc.; each of X to Z represents a C 1-8 alkyl or alkoxy group, C 2-6 alkenyl group, halogen atom, cyano group, or CH 2 ═CR 3 —COO—; each of R 1 to R 3 represents a hydrogen atom, methyl group, or halogen atom; each of L 1 to L 3 represents —CH 2 CH 2 COO—, —COO—, —OCO—, —CH 2 CH 2 —, —O(CH 2 ) f — (herein, f=1-8), etc.; n represents 0 or 1; and a to c represent such numbers that the polymerizable compound has at least one or more of any of X, Y, and Z.)

  本发明的可聚合化合物由下式（1）表示，可提供一种在接近常温下可聚合且在低温下存在液晶相的组合物。本发明的可聚合化合物的（共）聚合物和组成该聚合物的液晶物质是有用的光学各向异性材料。（在式中，环A1到A3分别表示苯环、环己烷环等；X到Z分别表示C1-8烷基或烷氧基、C2-6烯基、卤素原子、氰基或CH2═CR3—COO—；R1到R3分别表示氢原子、甲基或卤素原子；L1到L3分别表示—CH2CH2COO—、—COO—、—OCO—、—CH2CH2—、—O(CH2)f—（此处，f=1-8）等；n表示0或1；a到c表示聚合物至少具有X、Y和Z中的任意一种或多种。）
• Polymerizable compounds
  申请人：Adeka Corporation

  公开号：US07754912B2

  公开（公告）日：2010-07-13

  A novel polymerizable compound of the present invention is represented by the following general formula (I). Due to the presence of a reactive phenolic hydroxyl group at the end of the molecule, it can be reacted easily with various functional compounds and is useful as a monomer and an intermediate for various functional materials, especially as an intermediate for a polymerizable liquid crystal material. wherein R1 is a hydrogen atom, a methyl group or a halogen atom; R2 is an optionally substituted alkyl group having 1 to 6 carbon atoms, an optionally substituted alkoxy group having 1 to 6 carbon atoms, a halogen atom or a cyano group; an alkylene group of each of the alkyl and the alkoxy group may be interrupted by an unsaturated bond, an ether bond, a thioether bond or an ester bond; n is an integer from 0 to 14; and m is 0 or 1.

  本发明的一种新型可聚合化合物由下列通式(I)表示。由于分子末端存在反应性酚羟基，因此可以轻易地与各种功能化合物反应，并且可用作各种功能材料的单体和中间体，特别是可用作聚合型液晶材料的中间体。其中，R1是氢原子、甲基基团或卤素原子；R2是1至6个碳原子的可选取代的烷基基团、可选取代的烷氧基团、卤素原子或氰基；烷基和烷氧基的每个烷基烷氧基可以被不饱和键、醚键、硫醚键或酯键所中断；n为0至14的整数；m为0或1。
• Polymerizable compound and composition containing the polymerizable compound
  申请人：Adeka Corporation

  公开号：US07683203B2

  公开（公告）日：2010-03-23

  The polymerizable compound of the present invention is represented by general formula (1) below and can provide a composition that is polymerizable near ambient temperature and exists in a liquid crystal phase at low temperatures. The composition and a (co)polymer of the polymerizable compound of the present invention are liquid crystal substances useful as optically anisotropic materials. (In the formula, each of rings A1 to A3 represents a benzene ring, cyclohexane ring, etc.; each of X to Z represents a C1-8 alkyl or alkoxy group, C2-6 alkenyl group, halogen atom, cyano group, or CH2═CR3—COO—; each of R1 to R3 represents a hydrogen atom, methyl group, or halogen atom; each of L1 to L3 represents —CH2CH2COO—, —COO—, —OCO—, —CH2CH2—, —O(CH2)f— (herein, f=1-8), etc.; n represents 0 or 1; and a to c represent such numbers that the polymerizable compound has at least one or more of any of X, Y, and Z).

  本发明的可聚合化合物由下式（1）所表示，可提供一种在接近室温时可聚合且在低温下存在液晶相的组合物。本发明的可聚合化合物的（共）聚合物和组合物是有用的光学各向异性材料。（在式中，环A1到A3分别表示苯环、环己烷环等；X到Z分别表示C1-8烷基或烷氧基、C2-6烯基、卤素原子、氰基或CH2═CR3—COO—；R1到R3分别表示氢原子、甲基或卤素原子；L1到L3分别表示—CH2CH2COO—、—COO—、—OCO—、—CH2CH2—、—O(CH2)f—（此处，f=1-8）等；n表示0或1；a到c表示使可聚合化合物具有至少一个或多个X、Y和Z中的任何一个的数字）。