bis[(8-(p-trifluoromethyl)phenylnaphthylimino)acenaphthene] | 1609159-00-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: bis[(8-(p-trifluoromethyl)phenylnaphthylimino)acenaphthene]
• 英文别名: 1-N,2-N-bis[8-[4-(trifluoromethyl)phenyl]naphthalen-1-yl]acenaphthylene-1,2-diimine
• CAS: 1609159-00-3
• 化学式: C₄₆H₂₆F₆N₂
• 分子量: 720.716
• InChiKey: QAPJSNOQGNRKND-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.4
• 重原子数：
  54
• 可旋转键数：
  4
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  24.7
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  chloromethyl(1,5-cyclooctadiene)palladium(II) 、 bis[(8-(p-trifluoromethyl)phenylnaphthylimino)acenaphthene] 以 二氯甲烷 为溶剂， 反应 40.0h， 以63%的产率得到C₄₇H₂₉ClF₆N₂Pd
  参考文献：
  名称：

  “三明治”二亚胺-钯催化剂催化烯烃异构化

  摘要：

  In contrast to traditional diimine-palladium complexes, sterically hindered "sandwich" diimine-palladium adducts act as olefin-isomerization catalysts. Terminal olefins are selectively converted to 2-olefins by a sequence of migratory insertion,,6-hydride elimination, and olefin displacement. The reaction is performed at 0 degrees C with 1 mol % of an air-stable precatalyst and tolerates functional groups such as ketones, silyl ethers, and halogens. The isomerization may be used to produce silyl enol ethers from protected allylic alcohols.

  DOI：

  10.1021/acs.organomet.6b00856
• 作为产物：
  描述：

  N-(8-(4-(trifluoromethyl)phenyl)-naphthalen-1-yl)picolinamide 在 水 、 potassium oxalate 、 溶剂黄146 、 potassium hydroxide 作用下， 以 乙醇 、 水 为溶剂， 反应 38.5h， 生成 bis[(8-(p-trifluoromethyl)phenylnaphthylimino)acenaphthene]
  参考文献：
  名称：

  Secondary Alkene Insertion and Precision Chain-Walking: A New Route to Semicrystalline “Polyethylene” from α-Olefins by Combining Two Rare Catalytic Events

  摘要：

  While traditional polymerization of linear alpha-olefins (LAOs) typically provides amorphous, low T-g polymers, chain-straightening polymerization represents a route to semicrystalline materials. A series of alpha-diimine nickel catalysts were tested for the polymerization of various LAOs. Although known systems yielded amorphous or low-melting polymers, the "sandwich" alpha-diimines 3-6 yielded semicrystalline "polyethylene" comprised primarily of unbranched repeat units via a combination of uncommon regioselective 2,1-insertion and precision chain-walking events.

  DOI：

  10.1021/ja502130w