| 1418135-57-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• CAS: 1418135-57-5
• 化学式: C₂₁H₁₈
• 分子量: 270.374
• InChiKey: COLSBKABFPTITO-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  、 对硝基苯磺酰氯 在 tris(2,2'-bipyridyl)ruthenium dichloride 、 sodium carbonate 作用下， 以 乙腈 为溶剂， 反应 36.0h， 以46%的产率得到1-(1,1-dimethyl-3-(4-nitrophenyl)-1H-inden-2-yl)naphthalene
  参考文献：
  名称：

  Reusable Visible Light Photoredox Catalysts; Catalyzed Benzylic C(sp3)–H Functionalization/Carbocyclization Reactions

  摘要：

  The C(sp(3))-H functionalization/carbocyclization reaction through the oxidative quenching of visible light photoredox catalysts is established for constructing functionalized 1H-indenes. The process is general for a wide range of benzylic C(sp(3))-H bonds and is highly compatible with common functional groups. Importantly, the visible light photoredox catalysts can be recovered and reused at least three times without loss of catalytic activity.

  DOI：

  10.1055/s-0032-1317349