1-methyl-N-phenylnaphthalen-2-amine | 108981-26-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-methyl-N-phenylnaphthalen-2-amine
• 英文别名: (1-methyl-[2]naphthyl)-phenyl-amine；2-Anilino-1-methyl-naphthalin
• CAS: 108981-26-6
• 化学式: C₁₇H₁₅N
• 分子量: 233.313
• InChiKey: LFMVVYNCEVQSMW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-methyl-N-phenylnaphthalen-2-amine 在 三氯化砷 作用下， 生成 12-chloro-6-methyl-5,12-dihydro-benzo[b]phenarsazine
  参考文献：
  名称：

  Buu-Hoi; Hiong-Ki-Wei; Royer, Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1945, vol. 220, p. 361

  摘要：

  DOI：
• 作为产物：
  描述：

  2-羟基-1-萘甲醛 在 盐酸 、 amalgamated zinc 、 碘 、 溶剂黄146 作用下， 生成 1-methyl-N-phenylnaphthalen-2-amine
  参考文献：
  名称：

  Buu-Hoi; Hiong-Ki-Wei; Royer, Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1945, vol. 220, p. 361

  摘要：

  DOI：

文献信息

• 10.1002/adsc.202400281
  作者：Voronov, Aleksandr、Casnati, Alessandra、Hoch, Matteo、Pancrazzi, Francesco、Pio Mazzeo, Paolo、Merli, Daniele、Maestri, Giovanni、Pál Fehér, Péter、Stirling, András、Capaldo, Luca、Della Ca', Nicola

  DOI：10.1002/adsc.202400281

  日期：——

  The dearomatization of aromatic substrates via photocatalytic methodologies has gained escalating prominence to access molecular complexity. Although much focus has been put on non-active arenes, naphthols and N-based heteroaromatics, arylamines have so far remained in the background. Herein, we report a photocatalytic strategy for the aerobic, dearomative hydroxylation of naphthylamines under visible-light

  通过光催化方法对芳香族底物进行脱芳烃化已经获得了越来越重要的关注，以达到分子复杂性。尽管人们将大量注意力放在非活性芳烃、萘酚和 N 基杂芳烃上，但迄今为止，芳胺仍处于背景中。在此，我们报道了一种在可见光照射下萘胺的有氧、脱氢羟基化的光催化策略。我们的研究强调了单线态氧的产生是芳香性破坏的可行机制，减轻了由目标芳胺直接氧化引起的选择性问题。最后，我们在后期多元化活动中展示了所获得的脱芳烃产品的合成价值。
• ENCAPSULATED STABILIZER COMPOSITIONS
  申请人：Cytec Industries Inc.

  公开号：EP3328929A1

  公开（公告）日：2018-06-06
• [EN] NOVEL ORGANIC ELECTROLUMINESCENT COMPOUNDS AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME<br/>[FR] COMPOSÉS ORGANIQUES ÉLECTROLUMINESCENTS INNOVANTS ET DISPOSITIF ORGANIQUE ÉLECTROLUMINESCENT LES UTILISANT
  申请人：DOW ADVANCED DISPLAY MATERIALS

  公开号：WO2010107244A2

  公开（公告）日：2010-09-23

  Disclosed are a novel organic electroluminescent compound and an organic electroluminescent device comprising the same. When used as host material of organic electroluminescent material of an OLED device, the disclosed organic electroluminescent compound exhibits high luminous efficiency and excellent life property of the material as compared to conventional host material. Therefore, it can be used to manufacture OLEDs having very good operation life.
• [EN] ENCAPSULATED STABILIZER COMPOSITIONS<br/>[FR] COMPOSITIONS ENCAPSULÉES DE STABILISANT
  申请人：CYTEC IND INC

  公开号：WO2017023755A1

  公开（公告）日：2017-02-09

  Resin masterbatch compositions are provided as closed end pellets having a core including at least one additive and an outer layer comprising a polymer encapsulating the core, in which the thickness of the outer layer if from 0.001 mm to 1 cm. A stabilized composition is prepared from an organic material to be stabilized and the resin masterbatch composition. A process for producing the resin masterbatch composition includes co-extruding in tubular form a core material encapsulated by an outer layer, wherein the core material comprises at least one additive, and the outer layer comprises a polymer, to form a filled tube; passing the filled tube into a sealing device that cuts the filled tube into multiple discrete segments seals and simultaneously seals each end of each discrete segment, thereby forming closed end pellets; and cooling the closed end pellets.
• Buu-Hoi; Hiong-Ki-Wei; Royer, Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1945, vol. 220, p. 361
  作者：Buu-Hoi、Hiong-Ki-Wei、Royer

  DOI：——

  日期：——