magnesium(II) meso-tetra(fluoren-2-yl)porphyrinate | 159396-48-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: magnesium(II) meso-tetra(fluoren-2-yl)porphyrinate
• CAS: 159396-48-2
• 化学式: C₇₂H₄₄MgN₄
• 分子量: 989.473
• InChiKey: HHRZSHVFRRIFBQ-YHWFFDSRSA-N

反应信息

• 作为产物：
  描述：

  meso-5,10,15,20-tetrakis(fluoren-2-yl)porphyrin 在 magnesium bromide ethyl etherate 、 三乙胺 作用下， 以 三氯苯 为溶剂， 反应 2.0h， 以89%的产率得到magnesium(II) meso-tetra(fluoren-2-yl)porphyrinate
  参考文献：
  名称：

  Luminescence properties of fluorene-substituted porphyrinates of magnesium(II) and aluminum(III)

  摘要：

  Aluminum(III) (AlClTFP) and magnesium(II) (MgTFP) porphyrinates were synthesized from free meso-tetra(fluoren-2-yl)porphyrin, aluminum chloride and the MgBr2Et2O complex. The structure of the synthesized compounds was established on the basis NMR and absorption spectroscopy data. The luminescence properties of the new compounds were studied in a toluene solution at 300 K, and the quantum yields of fluorescence were determined by relative method. The quantum yields of fluorescence of MgTFP and AlClTFP (37 and 35%, respectively) are higher than that of parent porphyrin (22%).

  DOI：

  10.1134/s001814391002013x