| 1357019-01-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二氮杂萘
• CAS: 1357019-01-2
• 化学式: CF₃O₃S*C₂₂H₂₁N₂
• 分子量: 462.493
• InChiKey: PSJNZPOCWIJWRR-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  以 氘代氯仿 为溶剂， 生成 2-Phenylquinoline;trifluoromethanesulfonic acid
  参考文献：
  名称：

  About the intermediacy of 1,2-dihydroquinazolinium salts in the Friedländer–Borsche synthesis of quinolinium salts in acidic medium

  摘要：

  Spontaneously or under various heating conditions, 2-alkyl- or 2-aryl-(iminoalkyl)benzenamines react with ketones and triflic acid (1:1:1) to give quinolinium salts. When working under milder thermal conditions, intermediate 1,2-dihydroquinazolinium derivatives can be isolated or detected in solution but decompose upon standing or heating to give the corresponding quinolinium salts. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.09.053
• 作为产物：
  描述：

  三氟甲磺酸 、 苯乙酮 、 2-[(4-甲基苯基)亚氨基甲基]苯胺 以 氘代氯仿 为溶剂， 生成
  参考文献：
  名称：

  About the intermediacy of 1,2-dihydroquinazolinium salts in the Friedländer–Borsche synthesis of quinolinium salts in acidic medium

  摘要：

  Spontaneously or under various heating conditions, 2-alkyl- or 2-aryl-(iminoalkyl)benzenamines react with ketones and triflic acid (1:1:1) to give quinolinium salts. When working under milder thermal conditions, intermediate 1,2-dihydroquinazolinium derivatives can be isolated or detected in solution but decompose upon standing or heating to give the corresponding quinolinium salts. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.09.053