methyl-n-heptyldiallylammonium bromide | 133833-05-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: methyl-n-heptyldiallylammonium bromide
• 英文别名: heptyl-methyl-bis(prop-2-enyl)azanium;bromide
• CAS: 133833-05-3
• 化学式: Br*C₁₄H₂₈N
• 分子量: 290.287
• InChiKey: NYWZLPOZGIKYMG-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.78
• 重原子数：
  16.0
• 可旋转键数：
  10.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  N-甲基二烯丙基胺 、 1-溴代庚烷 以 丙酮 为溶剂， 反应 432.0h， 以60%的产率得到methyl-n-heptyldiallylammonium bromide
  参考文献：
  名称：

  Synthesis and catalytic properties of hydrophobically modified poly(alkylmethyldiallylammonium bromides)

  摘要：

  A series of hydrophobically modified homo- and copolymers of the poly(alkylmethyldiallylammonium bromide) type has been prepared by free-radical cyclo(co)polymerization of alkylmethyldiallylammonium bromide monomers in aqueous solution. Depending on the length of the alkyl side chain (varied between C1 and C-12) and the conformational freedom of the polymeric main chain, polysoap behavior was found as indicated by the hypsochromic shift of the long-wavelength absorption band of Methyl Orange, noncovalently bound to the macromolecule. The formation of a compact coil results in the presence of hydrophobic microdomains. Polysoap formation, akin to intramolecular micellization, is also revealed by appreciable catalytic effects on the unimolecular decarboxylation of 6-nitrobenzisoxazole-3-carboxylate at pH 11.3 and 30-degrees-C.

  DOI：

  10.1021/jo00013a043

文献信息

• YANG, YA JIANG;ENGBERTS, JAN B. F. N., J. ORG. CHEM., 56,(1991) N3, C. 4300-4304
  作者：YANG, YA JIANG、ENGBERTS, JAN B. F. N.

  DOI：——

  日期：——