phenyl 3,5-bis(benzyloxy)benzoate | 134739-08-5

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: phenyl 3,5-bis(benzyloxy)benzoate
• 英文别名: phenyl 3,5-bis(phenylmethoxy)benzoate
• CAS: 134739-08-5
• 化学式: C₂₇H₂₂O₄
• 分子量: 410.469
• InChiKey: BUSHSEGWXQQWGJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.06
• 重原子数：
  31.0
• 可旋转键数：
  8.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  44.76
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  phenyl 3,5-bis(benzyloxy)benzoate 在 palladium on activated charcoal 吡啶 、 4-二甲氨基吡啶 、 氢气 、 sodium carbonate 作用下， 以 四氢呋喃 为溶剂， 反应 17.25h， 生成 phenyl 3,5-bis(benzoyloxy)benzoate
  参考文献：
  名称：

  One-step synthesis of hyperbranched dendritic polyesters

  摘要：

  The one-step synthesis of a hyperbranched polyester possessing a dendritic structure has been achieved by thermal self-condensation of 3,5-bis(trimethylsiloxy)benzoyl chloride. The hyperbranched polyesters are obtained in yields of 80% or greater and with polystyrene equivalent weight average molecular weights in the range 30 000 to almost 200 000. The polydispersity and the molecular weights of the polyesters were found to vary greatly with the temperature of the polymerization. Characterization of the polymers was readily accomplished by NMR spectroscopy with the help of model compounds. The degree of branching of the polyesters as determined from NMR experiments was between 55 and 60%. The polyesters, which contain reactive functional groups at all chain extremities, are glassy materials that show a very high thermal stability comparable to that of analogous linear materials. In contrast, the excellent solubility properties of the hyperbranched polyesters influenced by their shape and functionalization are at variance with those of their linear polyester analogues.

  DOI：

  10.1021/ja00012a030
• 作为产物：
  描述：

  3,5-二羟基苯甲酸 在 4-二甲氨基吡啶 、 氢氧化钾 、 18-冠醚-6 、 potassium carbonate 、 N,N'-二环己基碳二亚胺 作用下， 以 四氢呋喃 、 乙醇 、 水 、 丙酮 为溶剂， 反应 54.0h， 生成 phenyl 3,5-bis(benzyloxy)benzoate
  参考文献：
  名称：

  One-step synthesis of hyperbranched dendritic polyesters

  摘要：

  The one-step synthesis of a hyperbranched polyester possessing a dendritic structure has been achieved by thermal self-condensation of 3,5-bis(trimethylsiloxy)benzoyl chloride. The hyperbranched polyesters are obtained in yields of 80% or greater and with polystyrene equivalent weight average molecular weights in the range 30 000 to almost 200 000. The polydispersity and the molecular weights of the polyesters were found to vary greatly with the temperature of the polymerization. Characterization of the polymers was readily accomplished by NMR spectroscopy with the help of model compounds. The degree of branching of the polyesters as determined from NMR experiments was between 55 and 60%. The polyesters, which contain reactive functional groups at all chain extremities, are glassy materials that show a very high thermal stability comparable to that of analogous linear materials. In contrast, the excellent solubility properties of the hyperbranched polyesters influenced by their shape and functionalization are at variance with those of their linear polyester analogues.

  DOI：

  10.1021/ja00012a030

文献信息

• HAWKER, C. J.;LEE, R.;FRECHET, J. M. J., J. AMER. CHEM. SOC., 113,(1991) N2, C. 4583-4588
  作者：HAWKER, C. J.、LEE, R.、FRECHET, J. M. J.

  DOI：——

  日期：——